Synthesis and luminescence behavior of rhenium(I) triynyl complexes. X-ray crystal structures of [Re(CO)3(tBu2bpy)(C=C-C=C-C=CPh)]and [Re(CO)3(Me2bpy)(C=C-C=C-C=CSiMe3)]

Research output: Journal Publications and Reviews (RGC: 21, 22, 62)21_Publication in refereed journalpeer-review

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Author(s)

  • Vivian Wing-Wah Yam
  • Samuel Hung-Fai Chong
  • Chi-Chiu Ko
  • Kung-Kai Cheung

Detail(s)

Original languageEnglish
Pages (from-to)5092-5097
Journal / PublicationOrganometallics
Volume19
Issue number24
Publication statusPublished - 27 Nov 2000
Externally publishedYes

Abstract

Luminescent rhenium(I) triynyl complexes [Re(CO)3(tBu2bpy)(C-C-C=C-C=CPh)] 1, [Re(CO)3(tBu2bpy)(C=C-C=C-C=CSiMe3)] 2, and [Re(CO)3(Me2bpy)(C=C-C=C-C= CSiMe3)] 3, were synthesized and their photophysical and electrochemical properties studied. The X-ray crystal structures of 1 and 3 have also been determined. A comparison study of their emission properties to that of their mono- and diynyl analogues was made and their emission origin suggested and supported by EHMO studies. © 2000 American Chemical Society.

Citation Format(s)

Synthesis and luminescence behavior of rhenium(I) triynyl complexes. X-ray crystal structures of [Re(CO)3(tBu2bpy)(C=C-C=C-C=CPh)]and [Re(CO)3(Me2bpy)(C=C-C=C-C=CSiMe3)]. / Yam, Vivian Wing-Wah; Chong, Samuel Hung-Fai; Ko, Chi-Chiu; Cheung, Kung-Kai.

In: Organometallics, Vol. 19, No. 24, 27.11.2000, p. 5092-5097.

Research output: Journal Publications and Reviews (RGC: 21, 22, 62)21_Publication in refereed journalpeer-review