Synthesis and crystal structure of a tetranuclear mixed-metal alkylidene complex CpWOs3(CO)9(μ-O)(μ-H)(μ-CHTol)

Shie-Ming Peng; Gene-Hsiang Lee; Yun Chi

doi:10.1016/S0277-5387(00)86756-X

Author(s)

Shie-Ming Peng
Gene-Hsiang Lee
Yun Chi

Detail(s)

Original language	English
Pages (from-to)	1491-1495
Journal / Publication	Polyhedron
Volume	9
Issue number	12
Publication status	Published - 1990
Externally published	Yes

Link(s)

DOI	DOI https://doi.org/10.1016/S0277-5387(00)86756-X Final Published version
	Check@CityULib
Link to Scopus	https://www.scopus.com/record/display.uri?eid=2-s2.0-33744645921&origin=recordpage
Permanent Link	https://scholars.cityu.edu.hk/en/publications/publication(a6d9d7b9-a730-4d0d-9068-121e87f29d6a).html

Abstract

The solid-state structure of a tetranuclear mixed-metal cluster CpWOs₃(CO)₉(μ-O)(μ-H)(μ-CHTol) (2) which possesses a bridging hydride, a bridging oxo and a bridging tolylalkylidene ligand is presented. Complex 2 crystallizes in the triclinic space group P1 , with a = 9.763(5), b = 10.759(4), c = 13.336(3) Å, α = 88.00(3), β = 108.56(3), γ = 100.44(3)°, Z = 2 ; 3463 observed reflections with I > 3σ(I) were used in the refinement. The R values converged to R_F = 0.057, R_w = 0.058.

Citation Format(s)

[ RIS ] [ BibTeX ]

Synthesis and crystal structure of a tetranuclear mixed-metal alkylidene complex CpWOs₃(CO)₉(μ-O)(μ-H)(μ-CHTol). / Peng, Shie-Ming; Lee, Gene-Hsiang; Chi, Yun.
In: Polyhedron, Vol. 9, No. 12, 1990, p. 1491-1495.

Research output: Journal Publications and Reviews › RGC 21 - Publication in refereed journal › peer-review

Peng, S-M, Lee, G-H & Chi, Y 1990, 'Synthesis and crystal structure of a tetranuclear mixed-metal alkylidene complex CpWOs₃(CO)₉(μ-O)(μ-H)(μ-CHTol)', Polyhedron, vol. 9, no. 12, pp. 1491-1495. https://doi.org/10.1016/S0277-5387(00)86756-X

Peng, S.-M., Lee, G.-H., & Chi, Y. (1990). Synthesis and crystal structure of a tetranuclear mixed-metal alkylidene complex CpWOs₃(CO)₉(μ-O)(μ-H)(μ-CHTol). Polyhedron, 9(12), 1491-1495. https://doi.org/10.1016/S0277-5387(00)86756-X

Peng SM, Lee GH, Chi Y. Synthesis and crystal structure of a tetranuclear mixed-metal alkylidene complex CpWOs₃(CO)₉(μ-O)(μ-H)(μ-CHTol). Polyhedron. 1990;9(12):1491-1495. doi: 10.1016/S0277-5387(00)86756-X

Peng, Shie-Ming ; Lee, Gene-Hsiang ; Chi, Yun. / Synthesis and crystal structure of a tetranuclear mixed-metal alkylidene complex CpWOs₃(CO)₉(μ-O)(μ-H)(μ-CHTol). In: Polyhedron. 1990 ; Vol. 9, No. 12. pp. 1491-1495.