Synthesis and crystal structure of a dioxo heterometallic complex CpWOs3(CO)9(μ-O)2(μ-H) (Cp=η-C5H5)

Research output: Journal Publications and Reviews (RGC: 21, 22, 62)21_Publication in refereed journalpeer-review

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  • Yun Chi
  • Ling-shwu Hwang
  • Gene-Hsiang Lee
  • Shie-Ming Peng


Original languageEnglish
Pages (from-to)1456-1457
Journal / PublicationJournal of the Chemical Society, Chemical Communications
Issue number22
Publication statusPublished - 15 Nov 1988
Externally publishedYes


The dioxo complex CpWOs3(CO)9(μ-O)2(μ-H) (Cp = η-C5H5) has been prepared from CpWOs3(CO)12(μ-H) by treatment with Me3NO and then 95% ethanol; the crystal structure has been determined, suggesting the presence of unique bridging oxo ligands.