Synthesis and Characterization of the W-Os Heterometallic Complex Os3(CO)10(μ-H)(μ-η 3-C(=CHPh)C≡CW(O)2(C5Me5)): Evidence of Hydride Dislocation on a Triosmium Framework by Crystal Polymorphism

Te-Kun Huang; Yun Chi; Shie-Ming Peng; Gene-Hsiang Lee

doi:10.1021/om980957z

Synthesis and Characterization of the W-Os Heterometallic Complex Os₃(CO)₁₀(μ-H)(μ-η ³-C(=CHPh)C≡CW(O)₂(C₅Me₅)): Evidence of Hydride Dislocation on a Triosmium Framework by Crystal Polymorphism

Te-Kun Huang, Yun Chi, Shie-Ming Peng, Gene-Hsiang Lee

Research output: Journal Publications and Reviews › RGC 21 - Publication in refereed journal › peer-review

12 Citations (Scopus)

Abstract

The heterometallic compound Os₃(CO)₁₀(μ-H)(μ-η³-C(=CHPh)C≡CW(O)₂(C₅Me₅)) (1), which possesses a bridging hydride and a C≡CC=CHPh ligand, is obtained on addition of the diynyl complex (C₅Me₅)W(O)₂(C≡CC≡CPh) to Os₃(μ-H)₂(CO)₁₀. ¹H NMR spectra show the occurrence of three isomers at equilibrium in solution, of which two isomers have been unambiguously characterized by an X-ray diffraction study. During subsequent tests of reactivity we isolated Os₃(CO)₁₀(μ-σ:η²-C≡CCHCHPh)(μ-H) (2) and (C₅Me₅)W(μ-O)₂Os₃(CO)₉(μ-σ:η²-C≡CCHCHPh) (3) through two distinct processes initiated by removal of the (C₅Me₅)W(O)₂ fragment and decarbonylation, respectively.

Original language	English
Pages (from-to)	1675-1679
Journal	Organometallics
Volume	18
Issue number	9
DOIs	https://doi.org/10.1021/om980957z
Publication status	Published - 1 Apr 1999
Externally published	Yes

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@article{2538c50c75cb479e94185129679a0cf9,

title = "Synthesis and Characterization of the W-Os Heterometallic Complex Os3(CO)10(μ-H)(μ-η 3-C(=CHPh)C≡CW(O)2(C5Me5)): Evidence of Hydride Dislocation on a Triosmium Framework by Crystal Polymorphism",

abstract = "The heterometallic compound Os3(CO)10(μ-H)(μ-η3-C(=CHPh)C≡CW(O)2(C5Me5)) (1), which possesses a bridging hydride and a C≡CC=CHPh ligand, is obtained on addition of the diynyl complex (C5Me5)W(O)2(C≡CC≡CPh) to Os3(μ-H)2(CO)10. 1H NMR spectra show the occurrence of three isomers at equilibrium in solution, of which two isomers have been unambiguously characterized by an X-ray diffraction study. During subsequent tests of reactivity we isolated Os3(CO)10(μ-σ:η2-C≡CCHCHPh)(μ-H) (2) and (C5Me5)W(μ-O)2Os3(CO)9(μ-σ:η2-C≡CCHCHPh) (3) through two distinct processes initiated by removal of the (C5Me5)W(O)2 fragment and decarbonylation, respectively.",

author = "Te-Kun Huang and Yun Chi and Shie-Ming Peng and Gene-Hsiang Lee",

year = "1999",

month = apr,

day = "1",

doi = "10.1021/om980957z",

language = "English",

volume = "18",

pages = "1675--1679",

journal = "Organometallics",

issn = "0276-7333",

publisher = "American Chemical Society",

number = "9",

}

Synthesis and Characterization of the W-Os Heterometallic Complex Os₃(CO)₁₀(μ-H)(μ-η ³-C(=CHPh)C≡CW(O)₂(C₅Me₅)): Evidence of Hydride Dislocation on a Triosmium Framework by Crystal Polymorphism. / Huang, Te-Kun; Chi, Yun; Peng, Shie-Ming et al.
In: Organometallics, Vol. 18, No. 9, 01.04.1999, p. 1675-1679.

Research output: Journal Publications and Reviews › RGC 21 - Publication in refereed journal › peer-review

TY - JOUR

T1 - Synthesis and Characterization of the W-Os Heterometallic Complex Os3(CO)10(μ-H)(μ-η 3-C(=CHPh)C≡CW(O)2(C5Me5))

T2 - Evidence of Hydride Dislocation on a Triosmium Framework by Crystal Polymorphism

AU - Huang, Te-Kun

AU - Chi, Yun

AU - Peng, Shie-Ming

AU - Lee, Gene-Hsiang

PY - 1999/4/1

Y1 - 1999/4/1

N2 - The heterometallic compound Os3(CO)10(μ-H)(μ-η3-C(=CHPh)C≡CW(O)2(C5Me5)) (1), which possesses a bridging hydride and a C≡CC=CHPh ligand, is obtained on addition of the diynyl complex (C5Me5)W(O)2(C≡CC≡CPh) to Os3(μ-H)2(CO)10. 1H NMR spectra show the occurrence of three isomers at equilibrium in solution, of which two isomers have been unambiguously characterized by an X-ray diffraction study. During subsequent tests of reactivity we isolated Os3(CO)10(μ-σ:η2-C≡CCHCHPh)(μ-H) (2) and (C5Me5)W(μ-O)2Os3(CO)9(μ-σ:η2-C≡CCHCHPh) (3) through two distinct processes initiated by removal of the (C5Me5)W(O)2 fragment and decarbonylation, respectively.

AB - The heterometallic compound Os3(CO)10(μ-H)(μ-η3-C(=CHPh)C≡CW(O)2(C5Me5)) (1), which possesses a bridging hydride and a C≡CC=CHPh ligand, is obtained on addition of the diynyl complex (C5Me5)W(O)2(C≡CC≡CPh) to Os3(μ-H)2(CO)10. 1H NMR spectra show the occurrence of three isomers at equilibrium in solution, of which two isomers have been unambiguously characterized by an X-ray diffraction study. During subsequent tests of reactivity we isolated Os3(CO)10(μ-σ:η2-C≡CCHCHPh)(μ-H) (2) and (C5Me5)W(μ-O)2Os3(CO)9(μ-σ:η2-C≡CCHCHPh) (3) through two distinct processes initiated by removal of the (C5Me5)W(O)2 fragment and decarbonylation, respectively.

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U2 - 10.1021/om980957z

DO - 10.1021/om980957z

M3 - RGC 21 - Publication in refereed journal

SN - 0276-7333

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JO - Organometallics

JF - Organometallics

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