Synthesis and characterization of luminescent osmium(II) carbonyl complexes based on chelating dibenzoylmethanate and halide ligands

Research output: Journal Publications and Reviews (RGC: 21, 22, 62)21_Publication in refereed journalpeer-review

21 Scopus Citations
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Author(s)

  • Yao-Lun Chen
  • Chittaranjan Sinha
  • I.-Chia Chen
  • Kuan-Lin Liu
  • Jen-Kan Yu
  • Pi-Tai Chou
  • Tian-Huey Lu

Detail(s)

Original languageEnglish
Pages (from-to)3046-3047
Journal / PublicationChemical Communications
Issue number24
Online published31 Oct 2003
Publication statusPublished - 2003
Externally publishedYes

Abstract

Octahedral Os(II) complexes 1-5 with formula [Os(CO)3X(dbm)] are prepared through utilization of both solid-state pyrolysis and ligand exchange reactions. These complexes exhibit prominent 3π-π* phosphorescence with unusually long lifetimes (29-64 μs) and high quantum yields (0.08-0.13).

Citation Format(s)

Synthesis and characterization of luminescent osmium(II) carbonyl complexes based on chelating dibenzoylmethanate and halide ligands. / Chen, Yao-Lun; Sinha, Chittaranjan; Chen, I.-Chia; Liu, Kuan-Lin; Chi, Yun; Yu, Jen-Kan; Chou, Pi-Tai; Lu, Tian-Huey.

In: Chemical Communications, No. 24, 2003, p. 3046-3047.

Research output: Journal Publications and Reviews (RGC: 21, 22, 62)21_Publication in refereed journalpeer-review