Synthesis and characterization of alkynylrhenium(I) tricarbonyl diimine complexes with fused thiophene and cyanoacrylic acid moiety

Siu-Tung Lam; Eric Chi-Ho Kwok; Vincent Chi-Chiu Ko; Mei-Yee Chan; Vivian Wing-Wah Yam

doi:10.1016/j.poly.2016.04.020

Synthesis and characterization of alkynylrhenium(I) tricarbonyl diimine complexes with fused thiophene and cyanoacrylic acid moiety

Siu-Tung Lam
, Eric Chi-Ho Kwok
, Vincent Chi-Chiu Ko
, Mei-Yee Chan
, Vivian Wing-Wah Yam^*

^*Corresponding author for this work

Research output: Journal Publications and Reviews › RGC 21 - Publication in refereed journal › peer-review

6 Citations (Scopus)

Abstract

A series of alkynylrhenium(I) tricarbonyl diimine complexes with fused thiophene and cyanoacrylic acid moiety has been synthesized and characterized. A long-lived charge separated state of these complexes have been found. Preliminary studies to explore the utilization of these complexes as photosensitizers have also been made, which show photoresponse upon light illumination.

Original language	English
Pages (from-to)	144-152
Journal	Polyhedron
Volume	116
DOIs	https://doi.org/10.1016/j.poly.2016.04.020
Publication status	Published - 2016

Research Keywords

Dyes/pigments
Energy conversion
Nanosecond transient absorption (TA) spectroscopy
Photosensitizers
Rhenium(I) complex

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10.1016/j.poly.2016.04.020

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title = "Synthesis and characterization of alkynylrhenium(I) tricarbonyl diimine complexes with fused thiophene and cyanoacrylic acid moiety",

abstract = "A series of alkynylrhenium(I) tricarbonyl diimine complexes with fused thiophene and cyanoacrylic acid moiety has been synthesized and characterized. A long-lived charge separated state of these complexes have been found. Preliminary studies to explore the utilization of these complexes as photosensitizers have also been made, which show photoresponse upon light illumination.",

keywords = "Dyes/pigments, Energy conversion, Nanosecond transient absorption (TA) spectroscopy, Photosensitizers, Rhenium(I) complex",

author = "Siu-Tung Lam and Kwok, \{Eric Chi-Ho\} and Ko, \{Vincent Chi-Chiu\} and Mei-Yee Chan and Yam, \{Vivian Wing-Wah\}",

year = "2016",

doi = "10.1016/j.poly.2016.04.020",

language = "English",

volume = "116",

pages = "144--152",

journal = "Polyhedron",

issn = "0277-5387",

publisher = "Elsevier Ltd.",

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TY - JOUR

T1 - Synthesis and characterization of alkynylrhenium(I) tricarbonyl diimine complexes with fused thiophene and cyanoacrylic acid moiety

AU - Lam, Siu-Tung

AU - Kwok, Eric Chi-Ho

AU - Ko, Vincent Chi-Chiu

AU - Chan, Mei-Yee

AU - Yam, Vivian Wing-Wah

PY - 2016

Y1 - 2016

N2 - A series of alkynylrhenium(I) tricarbonyl diimine complexes with fused thiophene and cyanoacrylic acid moiety has been synthesized and characterized. A long-lived charge separated state of these complexes have been found. Preliminary studies to explore the utilization of these complexes as photosensitizers have also been made, which show photoresponse upon light illumination.

AB - A series of alkynylrhenium(I) tricarbonyl diimine complexes with fused thiophene and cyanoacrylic acid moiety has been synthesized and characterized. A long-lived charge separated state of these complexes have been found. Preliminary studies to explore the utilization of these complexes as photosensitizers have also been made, which show photoresponse upon light illumination.

KW - Dyes/pigments

KW - Energy conversion

KW - Nanosecond transient absorption (TA) spectroscopy

KW - Photosensitizers

KW - Rhenium(I) complex

UR - https://www.scopus.com/pages/publications/84969945346

UR - https://www.scopus.com/record/pubmetrics.uri?eid=2-s2.0-84969945346&origin=recordpage

U2 - 10.1016/j.poly.2016.04.020

DO - 10.1016/j.poly.2016.04.020

M3 - RGC 21 - Publication in refereed journal

SN - 0277-5387

VL - 116

SP - 144

EP - 152

JO - Polyhedron

JF - Polyhedron

ER -

Synthesis and characterization of alkynylrhenium(I) tricarbonyl diimine complexes with fused thiophene and cyanoacrylic acid moiety

Abstract

Research Keywords

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