Synthesis and characterization of a tin(II) bis(phosphinoyl)methanediide complex: A stannavinylidene derivative

Jiayi Guo; Kai-Chung Lau; Hong-Wei Xi; Kok Hwa Lim; Cheuk-Wai So

doi:10.1039/b922377k

Synthesis and characterization of a tin(II) bis(phosphinoyl)methanediide complex: A stannavinylidene derivative

Jiayi Guo
, Kai-Chung Lau
, Hong-Wei Xi
, Kok Hwa Lim
, Cheuk-Wai So

Research output: Journal Publications and Reviews › RGC 21 - Publication in refereed journal › peer-review

29 Citations (Scopus)

Abstract

The reaction of [CH₂(PPh₂=NSiMe₃)(PPh ₂=S)] (1) with two equivalents of [Sn{N(SiMe₃) ₂}₂] in refluxing toluene afforded novel tin(II) bis(phosphinoyl)methanediide complex 3. The structure of compound 3 has been determined by X-ray crystallography and DFT calculations. The topological analysis of the electron densities of compound 3 was performed. © The Royal Society of Chemistry 2010.

Original language	English
Pages (from-to)	1929-1931
Journal	Chemical Communications
Volume	46
Issue number	11
DOIs	https://doi.org/10.1039/b922377k
Publication status	Published - 2010

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title = "Synthesis and characterization of a tin(II) bis(phosphinoyl)methanediide complex: A stannavinylidene derivative",

abstract = "The reaction of [CH2(PPh2=NSiMe3)(PPh 2=S)] (1) with two equivalents of [Sn\{N(SiMe3) 2\}2] in refluxing toluene afforded novel tin(II) bis(phosphinoyl)methanediide complex 3. The structure of compound 3 has been determined by X-ray crystallography and DFT calculations. The topological analysis of the electron densities of compound 3 was performed. {\textcopyright} The Royal Society of Chemistry 2010.",

author = "Jiayi Guo and Kai-Chung Lau and Hong-Wei Xi and Lim, \{Kok Hwa\} and Cheuk-Wai So",

year = "2010",

doi = "10.1039/b922377k",

language = "English",

volume = "46",

pages = "1929--1931",

journal = "Chemical Communications",

issn = "0009-241X",

publisher = "Royal Society of Chemistry",

number = "11",

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TY - JOUR

T1 - Synthesis and characterization of a tin(II) bis(phosphinoyl)methanediide complex

T2 - A stannavinylidene derivative

AU - Guo, Jiayi

AU - Lau, Kai-Chung

AU - Xi, Hong-Wei

AU - Lim, Kok Hwa

AU - So, Cheuk-Wai

PY - 2010

Y1 - 2010

N2 - The reaction of [CH2(PPh2=NSiMe3)(PPh 2=S)] (1) with two equivalents of [Sn{N(SiMe3) 2}2] in refluxing toluene afforded novel tin(II) bis(phosphinoyl)methanediide complex 3. The structure of compound 3 has been determined by X-ray crystallography and DFT calculations. The topological analysis of the electron densities of compound 3 was performed. © The Royal Society of Chemistry 2010.

AB - The reaction of [CH2(PPh2=NSiMe3)(PPh 2=S)] (1) with two equivalents of [Sn{N(SiMe3) 2}2] in refluxing toluene afforded novel tin(II) bis(phosphinoyl)methanediide complex 3. The structure of compound 3 has been determined by X-ray crystallography and DFT calculations. The topological analysis of the electron densities of compound 3 was performed. © The Royal Society of Chemistry 2010.

UR - https://www.scopus.com/pages/publications/77949416417

UR - https://www.scopus.com/record/pubmetrics.uri?eid=2-s2.0-77949416417&origin=recordpage

U2 - 10.1039/b922377k

DO - 10.1039/b922377k

M3 - RGC 21 - Publication in refereed journal

C2 - 20198256

SN - 0009-241X

VL - 46

SP - 1929

EP - 1931

JO - Chemical Communications

JF - Chemical Communications

IS - 11

ER -

Synthesis and characterization of a tin(II) bis(phosphinoyl)methanediide complex: A stannavinylidene derivative

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