Synthesis and Characterization of a (Ketenyl)metal Cluster Complex, an Intermediate in the Oxidative Decarbonation of an Acetylide Ligand

Te-Kun Huang; Yun Chi; Shie-Ming Peng; Gene-Hsiang Lee; Sue-Lein Wang; Fen-Liner Liao

doi:10.1021/om00005a014

Synthesis and Characterization of a (Ketenyl)metal Cluster Complex, an Intermediate in the Oxidative Decarbonation of an Acetylide Ligand

Te-Kun Huang
, Yun Chi
, Shie-Ming Peng
, Gene-Hsiang Lee
, Sue-Lein Wang
, Fen-Liner Liao

Research output: Journal Publications and Reviews › RGC 21 - Publication in refereed journal › peer-review

17 Citations (Scopus)

Abstract

Oxidation of the acetylide cluster Cp*WOs₃-(CO)₉(C₂)(C₂ph) (2) in toluene produced the ketenyl complex Cp*WOs₃(CO)₉(C₂)(OC₂Ph) (3). Compound 3 releases a CO group to afford the alkylidyne cluster Cp*WOs₃(CO)₉(C₂)(CPh) (4) upon heating, which provides an example of sequential conversion of acetylide to ketenyl and alkylidyne.

Original language	English
Pages (from-to)	2164-2166
Journal	Organometallics
Volume	14
Issue number	5
DOIs	https://doi.org/10.1021/om00005a014
Publication status	Published - 1 May 1995
Externally published	Yes

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title = "Synthesis and Characterization of a (Ketenyl)metal Cluster Complex, an Intermediate in the Oxidative Decarbonation of an Acetylide Ligand",

abstract = "Oxidation of the acetylide cluster Cp*WOs3-(CO)9(C2)(C2ph) (2) in toluene produced the ketenyl complex Cp*WOs3(CO)9(C2)(OC2Ph) (3). Compound 3 releases a CO group to afford the alkylidyne cluster Cp*WOs3(CO)9(C2)(CPh) (4) upon heating, which provides an example of sequential conversion of acetylide to ketenyl and alkylidyne. ",

author = "Te-Kun Huang and Yun Chi and Shie-Ming Peng and Gene-Hsiang Lee and Sue-Lein Wang and Fen-Liner Liao",

year = "1995",

month = may,

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doi = "10.1021/om00005a014",

language = "English",

volume = "14",

pages = "2164--2166",

journal = "Organometallics",

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TY - JOUR

T1 - Synthesis and Characterization of a (Ketenyl)metal Cluster Complex, an Intermediate in the Oxidative Decarbonation of an Acetylide Ligand

AU - Huang, Te-Kun

AU - Chi, Yun

AU - Peng, Shie-Ming

AU - Lee, Gene-Hsiang

AU - Wang, Sue-Lein

AU - Liao, Fen-Liner

PY - 1995/5/1

Y1 - 1995/5/1

N2 - Oxidation of the acetylide cluster Cp*WOs3-(CO)9(C2)(C2ph) (2) in toluene produced the ketenyl complex Cp*WOs3(CO)9(C2)(OC2Ph) (3). Compound 3 releases a CO group to afford the alkylidyne cluster Cp*WOs3(CO)9(C2)(CPh) (4) upon heating, which provides an example of sequential conversion of acetylide to ketenyl and alkylidyne.

AB - Oxidation of the acetylide cluster Cp*WOs3-(CO)9(C2)(C2ph) (2) in toluene produced the ketenyl complex Cp*WOs3(CO)9(C2)(OC2Ph) (3). Compound 3 releases a CO group to afford the alkylidyne cluster Cp*WOs3(CO)9(C2)(CPh) (4) upon heating, which provides an example of sequential conversion of acetylide to ketenyl and alkylidyne.

UR - https://www.scopus.com/pages/publications/0010927991

UR - https://www.scopus.com/record/pubmetrics.uri?eid=2-s2.0-0010927991&origin=recordpage

U2 - 10.1021/om00005a014

DO - 10.1021/om00005a014

M3 - RGC 21 - Publication in refereed journal

SN - 0276-7333

VL - 14

SP - 2164

EP - 2166

JO - Organometallics

JF - Organometallics

IS - 5

ER -

Synthesis and Characterization of a (Ketenyl)metal Cluster Complex, an Intermediate in the Oxidative Decarbonation of an Acetylide Ligand

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