TY - JOUR
T1 - Syntheses, crystal structures, photophysics and cation-binding studies of luminescent functionalized ruthenium polypyridine complexes with orthometallated aminocarbene ligands
AU - Yam, Vivian Wing-Wah
AU - Ko, Chi-Chiu
AU - Chu, Wai-Kin
AU - Zhu, Nianyong
PY - 2003/10/21
Y1 - 2003/10/21
N2 - A series of luminescent functionalized ruthenium polypyridine complexes with orthometallated aminocarbene ligands has been synthesized and their photophysical properties studied. The cation-binding properties of one crown-ether functionalized complexes have also been studied. The X-ray crystal structures of [Ru(bpy)2=C(CH2-B15C5)NHC6H3Br]OTf and [Ru(5,5′-Me2bpy)2=C(CH2Ph)NHC6 H3Br]OTf have been determined (bpy = 2,2′-bipyridine; 5,5′-Me2bpy = 5,5′-dimethyl-2,2′-bipyridine; B15C5 = benzo-15-crown-5).
AB - A series of luminescent functionalized ruthenium polypyridine complexes with orthometallated aminocarbene ligands has been synthesized and their photophysical properties studied. The cation-binding properties of one crown-ether functionalized complexes have also been studied. The X-ray crystal structures of [Ru(bpy)2=C(CH2-B15C5)NHC6H3Br]OTf and [Ru(5,5′-Me2bpy)2=C(CH2Ph)NHC6 H3Br]OTf have been determined (bpy = 2,2′-bipyridine; 5,5′-Me2bpy = 5,5′-dimethyl-2,2′-bipyridine; B15C5 = benzo-15-crown-5).
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UR - https://www.scopus.com/record/pubmetrics.uri?eid=2-s2.0-0142165749&origin=recordpage
M3 - RGC 21 - Publication in refereed journal
SN - 1477-9226
SP - 3914
EP - 3921
JO - Journal of the Chemical Society. Dalton Transactions
JF - Journal of the Chemical Society. Dalton Transactions
IS - 20
ER -