Syntheses and structures of novel heterobimetallic Cu(li)-Au(i) complexes Cu(cyclen)[Au(CN)2]2 and Cu(pyz)[Au(CN)2]2

Research output: Journal Publications and Reviews (RGC: 21, 22, 62)22_Publication in policy or professional journal

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Original languageEnglish
Pages (from-to)629-631
Journal / PublicationJournal of the Chemical Society, Dalton Transactions
Issue number5
Publication statusPublished - 2000

Abstract

Two novel cyano CuII-AuI bimetallic complexes, Cu(cyclen)[Au(CN)2]2 1 (cyclen = 1,4,7,10-tetraazacyclododecanc) and Cu(pyz)[Au(CN)2]2 2 (pyz = pyrazine) were prepared; 1 has a dimeric structure arising from Au1 ... Au1 interactions, while 2 consists of linear pyrazine-bridged copper chains intercalated to produce a 2-D pleated sheet structure. © The Royal Society of Chemistry 2000.

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