Syntheses and photophysical studies of new classes of luminescent isocyano rhenium(I) diimine complexes
Research output: Journal Publications and Reviews (RGC: 21, 22, 62) › 21_Publication in refereed journal › peer-review
Author(s)
Detail(s)
Original language | English |
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Pages (from-to) | 1546-1555 |
Journal / Publication | Coordination Chemistry Reviews |
Volume | 256 |
Issue number | 15-16 |
Publication status | Published - Aug 2012 |
Link(s)
Abstract
The rich excited state properties associated with the long-lived triplet metal-to-ligand charge transfer excited state of rhenium(I) tricarbonyl diimine complexes have been investigated for many years. Through judicious design and functionalization of the ligands with various functional moieties, these complexes can be used for different applications. However, further modification of the physical and excited state properties with their functions being maintained are challenging. In view of this, we have designed several new classes of isocyano rhenium(I) diimine complexes with readily tunable structural features. In this review article, our recent work on the syntheses, characterizations and photophysical properties of these tunable rhenium(I) diimine luminophores are discussed. © 2012 Elsevier B.V.
Research Area(s)
- Emission solvatochromism, Isocyanide, MLCT, Polypyridine complexes, Rhenium
Citation Format(s)
Syntheses and photophysical studies of new classes of luminescent isocyano rhenium(I) diimine complexes. / Ko, Chi-Chiu; Cheung, Apple Wai-Yi; Lo, Larry Tso-Lun et al.
In: Coordination Chemistry Reviews, Vol. 256, No. 15-16, 08.2012, p. 1546-1555.
In: Coordination Chemistry Reviews, Vol. 256, No. 15-16, 08.2012, p. 1546-1555.
Research output: Journal Publications and Reviews (RGC: 21, 22, 62) › 21_Publication in refereed journal › peer-review