Syntheses and crystal structures of binuclear ruthenium complexes bearing 1,8′-bis(diphenylphosphinomethyl)naphthalene

Chang-Bin Yu; Yu-Qing Xia; Xiao-Hong Tian; Xiang-Ge Zhou; Guang-Ying Fan; Rui-Xiang Li; Xian-Jun Li; Kim-Chung Tin; Ning-Bew Wong

doi:10.1016/j.jorganchem.2005.04.061

Syntheses and crystal structures of binuclear ruthenium complexes bearing 1,8′-bis(diphenylphosphinomethyl)naphthalene

Chang-Bin Yu
, Yu-Qing Xia
, Xiao-Hong Tian
, Xiang-Ge Zhou
, Guang-Ying Fan
, Rui-Xiang Li
, Xian-Jun Li
, Kim-Chung Tin
, Ning-Bew Wong

Research output: Journal Publications and Reviews › RGC 21 - Publication in refereed journal › peer-review

5 Citations (Scopus)

Abstract

Treatment of [RuCl₂(η⁶-C₆H ₆)]_x with bidentate phosphine ligand BDNA [1,8-bis(diphenylphosphinomethyl)naphthalene] in methanol at room temperature gave η⁶-benzene-ruthenium complexes Ru₂Cl ₄(η⁶-C₆H₆)₂(μ- BDNA) (1). Complex 1 further reacted with AgBF₄ to form complex [Ru₂Cl₂(μ-Cl)(η⁶-C₆H ₆)₂(μ-BDNA)](BF₄) (2). [RuCl ₂(η⁶-C₆H₆)]_x reacted with BDNA in refluxing methanol and then the reaction solution was treated with AgBF₄ to generate complex [Ru₂Cl₂(η ⁶-C₆H₆)₂(μ-BDNA) ₂](BF₄)₂ (3). Their compositions and structures had been determined by elemental analyses, NMR spectra and single crystal X-ray diffractions. X-ray diffraction showed that complex 1 belonged to monoclinic crystal system, P2₁/c space group with Z = 4, a = 12.810 Å, b = 21.507 Å, c = 18.471 Å, β = 107.95°; complex 2 belonged monoclinic crystal system, P2₁/n space group with Z = 4, a = 14.498 Å, b = 15.644 Å, c = 20.788 Å, β = 103.404°, and complex 3 belonged to monoclinic crystal system, P2₁/n space group with Z = 2, a = 13.732 Å, b = 14.351 Å, c = 19.733 Å, β = 94.82°. © 2005 Elsevier B.V. All rights reserved.

Original language	English
Pages (from-to)	499-506
Journal	Journal of Organometallic Chemistry
Volume	691
Issue number	3
DOIs	https://doi.org/10.1016/j.jorganchem.2005.04.061
Publication status	Published - 15 Jan 2006

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Publication details (e.g. title, author(s), publication statuses and dates) are captured on an “AS IS” and “AS AVAILABLE” basis at the time of record harvesting from the data source. Suggestions for further amendments or supplementary information can be sent to [email protected].

Funding

Financial support for this work by the National Science Foundation of China (No. 20271035, No. 20371032) is gratefully acknowledged.

Research Keywords

1,8′-Bis(diphenylphosphinomethyl)naphthalene
Binuclear complex
Ruthenium

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@article{d02250628c7f4a29affd71032ebe688c,

title = "Syntheses and crystal structures of binuclear ruthenium complexes bearing 1,8′-bis(diphenylphosphinomethyl)naphthalene",

abstract = "Treatment of [RuCl2(η6-C6H 6)]x with bidentate phosphine ligand BDNA [1,8-bis(diphenylphosphinomethyl)naphthalene] in methanol at room temperature gave η6-benzene-ruthenium complexes Ru2Cl 4(η6-C6H6)2(μ- BDNA) (1). Complex 1 further reacted with AgBF4 to form complex [Ru2Cl2(μ-Cl)(η6-C6H 6)2(μ-BDNA)](BF4) (2). [RuCl 2(η6-C6H6)]x reacted with BDNA in refluxing methanol and then the reaction solution was treated with AgBF4 to generate complex [Ru2Cl2(η 6-C6H6)2(μ-BDNA) 2](BF4)2 (3). Their compositions and structures had been determined by elemental analyses, NMR spectra and single crystal X-ray diffractions. X-ray diffraction showed that complex 1 belonged to monoclinic crystal system, P21/c space group with Z = 4, a = 12.810 {\AA}, b = 21.507 {\AA}, c = 18.471 {\AA}, β = 107.95°; complex 2 belonged monoclinic crystal system, P21/n space group with Z = 4, a = 14.498 {\AA}, b = 15.644 {\AA}, c = 20.788 {\AA}, β = 103.404°, and complex 3 belonged to monoclinic crystal system, P21/n space group with Z = 2, a = 13.732 {\AA}, b = 14.351 {\AA}, c = 19.733 {\AA}, β = 94.82°. {\textcopyright} 2005 Elsevier B.V. All rights reserved.",

keywords = "1,8′-Bis(diphenylphosphinomethyl)naphthalene, Binuclear complex, Ruthenium",

author = "Chang-Bin Yu and Yu-Qing Xia and Xiao-Hong Tian and Xiang-Ge Zhou and Guang-Ying Fan and Rui-Xiang Li and Xian-Jun Li and Kim-Chung Tin and Ning-Bew Wong",

note = "Publication details (e.g. title, author(s), publication statuses and dates) are captured on an “AS IS” and “AS AVAILABLE” basis at the time of record harvesting from the data source. Suggestions for further amendments or supplementary information can be sent to [email protected].",

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doi = "10.1016/j.jorganchem.2005.04.061",

language = "English",

volume = "691",

pages = "499--506",

journal = "Journal of Organometallic Chemistry",

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TY - JOUR

T1 - Syntheses and crystal structures of binuclear ruthenium complexes bearing 1,8′-bis(diphenylphosphinomethyl)naphthalene

AU - Yu, Chang-Bin

AU - Xia, Yu-Qing

AU - Tian, Xiao-Hong

AU - Zhou, Xiang-Ge

AU - Fan, Guang-Ying

AU - Li, Rui-Xiang

AU - Li, Xian-Jun

AU - Tin, Kim-Chung

AU - Wong, Ning-Bew

N1 - Publication details (e.g. title, author(s), publication statuses and dates) are captured on an “AS IS” and “AS AVAILABLE” basis at the time of record harvesting from the data source. Suggestions for further amendments or supplementary information can be sent to [email protected].

PY - 2006/1/15

Y1 - 2006/1/15

N2 - Treatment of [RuCl2(η6-C6H 6)]x with bidentate phosphine ligand BDNA [1,8-bis(diphenylphosphinomethyl)naphthalene] in methanol at room temperature gave η6-benzene-ruthenium complexes Ru2Cl 4(η6-C6H6)2(μ- BDNA) (1). Complex 1 further reacted with AgBF4 to form complex [Ru2Cl2(μ-Cl)(η6-C6H 6)2(μ-BDNA)](BF4) (2). [RuCl 2(η6-C6H6)]x reacted with BDNA in refluxing methanol and then the reaction solution was treated with AgBF4 to generate complex [Ru2Cl2(η 6-C6H6)2(μ-BDNA) 2](BF4)2 (3). Their compositions and structures had been determined by elemental analyses, NMR spectra and single crystal X-ray diffractions. X-ray diffraction showed that complex 1 belonged to monoclinic crystal system, P21/c space group with Z = 4, a = 12.810 Å, b = 21.507 Å, c = 18.471 Å, β = 107.95°; complex 2 belonged monoclinic crystal system, P21/n space group with Z = 4, a = 14.498 Å, b = 15.644 Å, c = 20.788 Å, β = 103.404°, and complex 3 belonged to monoclinic crystal system, P21/n space group with Z = 2, a = 13.732 Å, b = 14.351 Å, c = 19.733 Å, β = 94.82°. © 2005 Elsevier B.V. All rights reserved.

AB - Treatment of [RuCl2(η6-C6H 6)]x with bidentate phosphine ligand BDNA [1,8-bis(diphenylphosphinomethyl)naphthalene] in methanol at room temperature gave η6-benzene-ruthenium complexes Ru2Cl 4(η6-C6H6)2(μ- BDNA) (1). Complex 1 further reacted with AgBF4 to form complex [Ru2Cl2(μ-Cl)(η6-C6H 6)2(μ-BDNA)](BF4) (2). [RuCl 2(η6-C6H6)]x reacted with BDNA in refluxing methanol and then the reaction solution was treated with AgBF4 to generate complex [Ru2Cl2(η 6-C6H6)2(μ-BDNA) 2](BF4)2 (3). Their compositions and structures had been determined by elemental analyses, NMR spectra and single crystal X-ray diffractions. X-ray diffraction showed that complex 1 belonged to monoclinic crystal system, P21/c space group with Z = 4, a = 12.810 Å, b = 21.507 Å, c = 18.471 Å, β = 107.95°; complex 2 belonged monoclinic crystal system, P21/n space group with Z = 4, a = 14.498 Å, b = 15.644 Å, c = 20.788 Å, β = 103.404°, and complex 3 belonged to monoclinic crystal system, P21/n space group with Z = 2, a = 13.732 Å, b = 14.351 Å, c = 19.733 Å, β = 94.82°. © 2005 Elsevier B.V. All rights reserved.

KW - 1,8′-Bis(diphenylphosphinomethyl)naphthalene

KW - Binuclear complex

KW - Ruthenium

UR - https://www.scopus.com/pages/publications/29344441438

UR - https://www.scopus.com/record/pubmetrics.uri?eid=2-s2.0-29344441438&origin=recordpage

U2 - 10.1016/j.jorganchem.2005.04.061

DO - 10.1016/j.jorganchem.2005.04.061

M3 - RGC 21 - Publication in refereed journal

SN - 0022-328X

VL - 691

SP - 499

EP - 506

JO - Journal of Organometallic Chemistry

JF - Journal of Organometallic Chemistry

IS - 3

ER -

Syntheses and crystal structures of binuclear ruthenium complexes bearing 1,8′-bis(diphenylphosphinomethyl)naphthalene

Abstract

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