Switching Luminescent Properties in Osmium-Based β-Diketonate Complexes

Yao-Lun Chen; Shih-Wen Li; Yun Chi; Yi-Ming Cheng; Shih-Chieh Pu; Yu-Shan Yeh; Pi-Tai Chou

doi:10.1002/cphc.200500252

Switching Luminescent Properties in Osmium-Based β-Diketonate Complexes

Yao-Lun Chen
, Shih-Wen Li
, Yun Chi^*
, Yi-Ming Cheng
, Shih-Chieh Pu
, Yu-Shan Yeh
, Pi-Tai Chou^*

^*Corresponding author for this work

Research output: Journal Publications and Reviews › RGC 21 - Publication in refereed journal › peer-review

102 Citations (Scopus)

Abstract

Luminescent complexes: Through the design and synthesis of a series of new osmium‐based β‐diketonate carbonyl complexes (see picture; MLCT=metal‐to‐ligand charge transfer, k_isc=intersystem crossing constant), a remarkable aromatic tunable fluorescence/phosphorescence ratio was explored. The relative luminescent efficiencies and associated dynamics were evaluated.

Original language	English
Pages (from-to)	2012-2017
Journal	ChemPhysChem
Volume	6
Issue number	10
Online published	6 Oct 2005
DOIs	https://doi.org/10.1002/cphc.200500252
Publication status	Published - 14 Oct 2005
Externally published	Yes

Research Keywords

diketonate
fluorescence
intersystem crossing
osmium
phosphorescence

Access Output

10.1002/cphc.200500252

Other Access Options

Check CityUHK Library

Permanent Link

Right click to copy link

Cite this

@article{de46375c3853472fa662c1902d93175b,

title = "Switching Luminescent Properties in Osmium-Based β-Diketonate Complexes",

abstract = "Luminescent complexes: Through the design and synthesis of a series of new osmium‐based β‐diketonate carbonyl complexes (see picture; MLCT=metal‐to‐ligand charge transfer, kisc=intersystem crossing constant), a remarkable aromatic tunable fluorescence/phosphorescence ratio was explored. The relative luminescent efficiencies and associated dynamics were evaluated.",

keywords = "diketonate, fluorescence, intersystem crossing, osmium, phosphorescence",

author = "Yao-Lun Chen and Shih-Wen Li and Yun Chi and Yi-Ming Cheng and Shih-Chieh Pu and Yu-Shan Yeh and Pi-Tai Chou",

year = "2005",

month = oct,

day = "14",

doi = "10.1002/cphc.200500252",

language = "English",

volume = "6",

pages = "2012--2017",

journal = "ChemPhysChem",

issn = "1439-4235",

publisher = "Wiley-VCH Verlag GmbH",

number = "10",

}

TY - JOUR

T1 - Switching Luminescent Properties in Osmium-Based β-Diketonate Complexes

AU - Chen, Yao-Lun

AU - Li, Shih-Wen

AU - Chi, Yun

AU - Cheng, Yi-Ming

AU - Pu, Shih-Chieh

AU - Yeh, Yu-Shan

AU - Chou, Pi-Tai

PY - 2005/10/14

Y1 - 2005/10/14

N2 - Luminescent complexes: Through the design and synthesis of a series of new osmium‐based β‐diketonate carbonyl complexes (see picture; MLCT=metal‐to‐ligand charge transfer, kisc=intersystem crossing constant), a remarkable aromatic tunable fluorescence/phosphorescence ratio was explored. The relative luminescent efficiencies and associated dynamics were evaluated.

AB - Luminescent complexes: Through the design and synthesis of a series of new osmium‐based β‐diketonate carbonyl complexes (see picture; MLCT=metal‐to‐ligand charge transfer, kisc=intersystem crossing constant), a remarkable aromatic tunable fluorescence/phosphorescence ratio was explored. The relative luminescent efficiencies and associated dynamics were evaluated.

KW - diketonate

KW - fluorescence

KW - intersystem crossing

KW - osmium

KW - phosphorescence

UR - https://www.scopus.com/pages/publications/27144553105

UR - https://www.scopus.com/record/pubmetrics.uri?eid=2-s2.0-27144553105&origin=recordpage

U2 - 10.1002/cphc.200500252

DO - 10.1002/cphc.200500252

M3 - RGC 21 - Publication in refereed journal

SN - 1439-4235

VL - 6

SP - 2012

EP - 2017

JO - ChemPhysChem

JF - ChemPhysChem

IS - 10

ER -

Switching Luminescent Properties in Osmium-Based β-Diketonate Complexes

Abstract

Research Keywords

Access Output

Other Access Options

Permanent Link

Other Files and Links

Fingerprint

Cite this