Surprising activity for group 4 polyolefin catalysts [M{(OAr)2py}Cl2(thf)] (M = Zr, Ti) bearing tridentate pyridine-2,6-bis(aryloxide) ligands

Michael C. W. Chan; Ka-Ho Tam; Yung-Lin Pui; Nianyong Zhu

Surprising activity for group 4 polyolefin catalysts [M{(OAr)2py}Cl2(thf)] (M = Zr, Ti) bearing tridentate pyridine-2,6-bis(aryloxide) ligands

Michael C. W. Chan, Ka-Ho Tam, Yung-Lin Pui, Nianyong Zhu

Research output: Journal Publications and Reviews › RGC 21 - Publication in refereed journal › peer-review

Abstract

Unexpectedly high ethylene polymerisation activity is observed for zirconium(IV) catalysts supported by a rigid tridentate pyridine-bis(phenolate) ligand in conjunction with MAO; a methodology towards analogues with unsymmetric ligands and the significance of the coordinated solvent molecule are described.

Original language	English
Pages (from-to)	3085-3087
Journal	Journal of the Chemical Society, Dalton Transactions
Issue number	16
Publication status	Published - 2002
Externally published	Yes

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@article{d704dd9e7f9d430ca959d9d76bf57b16,

title = "Surprising activity for group 4 polyolefin catalysts [M{(OAr)2py}Cl2(thf)] (M = Zr, Ti) bearing tridentate pyridine-2,6-bis(aryloxide) ligands",

abstract = "Unexpectedly high ethylene polymerisation activity is observed for zirconium(IV) catalysts supported by a rigid tridentate pyridine-bis(phenolate) ligand in conjunction with MAO; a methodology towards analogues with unsymmetric ligands and the significance of the coordinated solvent molecule are described.",

author = "Chan, {Michael C. W.} and Ka-Ho Tam and Yung-Lin Pui and Nianyong Zhu",

year = "2002",

language = "English",

pages = "3085--3087",

journal = "Journal of the Chemical Society, Dalton Transactions",

issn = "1470-479X",

publisher = "Royal Society of Chemistry",

number = "16",

}

Surprising activity for group 4 polyolefin catalysts [M{(OAr)2py}Cl2(thf)] (M = Zr, Ti) bearing tridentate pyridine-2,6-bis(aryloxide) ligands. / Chan, Michael C. W.; Tam, Ka-Ho; Pui, Yung-Lin et al.
In: Journal of the Chemical Society, Dalton Transactions, No. 16, 2002, p. 3085-3087.

Research output: Journal Publications and Reviews › RGC 21 - Publication in refereed journal › peer-review

TY - JOUR

T1 - Surprising activity for group 4 polyolefin catalysts [M{(OAr)2py}Cl2(thf)] (M = Zr, Ti) bearing tridentate pyridine-2,6-bis(aryloxide) ligands

AU - Chan, Michael C. W.

AU - Tam, Ka-Ho

AU - Pui, Yung-Lin

AU - Zhu, Nianyong

PY - 2002

Y1 - 2002

N2 - Unexpectedly high ethylene polymerisation activity is observed for zirconium(IV) catalysts supported by a rigid tridentate pyridine-bis(phenolate) ligand in conjunction with MAO; a methodology towards analogues with unsymmetric ligands and the significance of the coordinated solvent molecule are described.

AB - Unexpectedly high ethylene polymerisation activity is observed for zirconium(IV) catalysts supported by a rigid tridentate pyridine-bis(phenolate) ligand in conjunction with MAO; a methodology towards analogues with unsymmetric ligands and the significance of the coordinated solvent molecule are described.

UR - http://www.scopus.com/inward/record.url?scp=0035982514&partnerID=8YFLogxK

UR - https://www.scopus.com/record/pubmetrics.uri?eid=2-s2.0-0035982514&origin=recordpage

M3 - RGC 21 - Publication in refereed journal

SN - 1470-479X

SP - 3085

EP - 3087

JO - Journal of the Chemical Society, Dalton Transactions

JF - Journal of the Chemical Society, Dalton Transactions

IS - 16

ER -

Surprising activity for group 4 polyolefin catalysts [M{(OAr)2py}Cl2(thf)] (M = Zr, Ti) bearing tridentate pyridine-2,6-bis(aryloxide) ligands

Abstract

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