Surface or Internal Hydration - Does It Really Matter?

Christian van der Linde; Milan Ončák; Ethan M. Cunningham; Wai Kit Tang; Chi-Kit Siu; Martin K. Beyer

doi:10.1021/jasms.2c00290

Author(s)

Christian van der Linde
Milan Ončák
Ethan M. Cunningham
Martin K. Beyer

Related Research Unit(s)

Department of Chemistry

Detail(s)

Original language	English
Pages (from-to)	337-354
Journal / Publication	Journal of the American Society for Mass Spectrometry
Volume	34
Issue number	3
Online published	6 Feb 2023
Publication status	Published - 1 Mar 2023

Link(s)

DOI	DOI https://doi.org/10.1021/jasms.2c00290 Final Published version
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Attachment(s)	Documents 136603291.pdf Final Published version, 12.8 MB, PDF Publisher's Copyright Statement This full text is made available under CC-BY 4.0. https://creativecommons.org/licenses/by/4.0/
Link to Scopus	https://www.scopus.com/record/display.uri?eid=2-s2.0-85147814183&origin=recordpage
Permanent Link	https://scholars.cityu.edu.hk/en/publications/publication(84fec6dc-ae71-437d-a4e3-b0ca623ed782).html

Abstract

The precise location of an ion or electron, whether it is internally solvated or residing on the surface of a water cluster, remains an intriguing question. Subtle differences in the hydrogen bonding network may lead to a preference for one or the other. Here we discuss spectroscopic probes of the structure of gas-phase hydrated ions in combination with quantum chemistry, as well as H/D exchange as a means of structure elucidation. With the help of nanocalorimetry, we look for thermochemical signatures of surface vs internal solvation. Examples of strongly size-dependent reactivity are reviewed which illustrate the influence of surface vs internal solvation on unimolecular rearrangements of the cluster, as well as on the rate and product distribution of ion-molecule reactions. © 2023 The Authors. Published by American Chemical Society.

Research Area(s)

Citation Format(s)

[ RIS ] [ BibTeX ]

Surface or Internal Hydration - Does It Really Matter? / van der Linde, Christian; Ončák, Milan; Cunningham, Ethan M. et al.
In: Journal of the American Society for Mass Spectrometry, Vol. 34, No. 3, 01.03.2023, p. 337-354.

Research output: Journal Publications and Reviews (RGC: 21, 22, 62) › 21_Publication in refereed journal › peer-review

van der Linde, C, Ončák, M, Cunningham, EM, Tang, WK , Siu, C-K & Beyer, MK 2023, 'Surface or Internal Hydration - Does It Really Matter?', Journal of the American Society for Mass Spectrometry, vol. 34, no. 3, pp. 337-354. https://doi.org/10.1021/jasms.2c00290

van der Linde, C., Ončák, M., Cunningham, E. M., Tang, W. K., Siu, C-K., & Beyer, M. K. (2023). Surface or Internal Hydration - Does It Really Matter? Journal of the American Society for Mass Spectrometry, 34(3), 337-354. https://doi.org/10.1021/jasms.2c00290

van der Linde C, Ončák M, Cunningham EM, Tang WK , Siu C-K, Beyer MK. Surface or Internal Hydration - Does It Really Matter? Journal of the American Society for Mass Spectrometry. 2023 Mar 1;34(3):337-354. Epub 2023 Feb 6. doi: 10.1021/jasms.2c00290

van der Linde, Christian ; Ončák, Milan ; Cunningham, Ethan M. et al. / Surface or Internal Hydration - Does It Really Matter?. In: Journal of the American Society for Mass Spectrometry. 2023 ; Vol. 34, No. 3. pp. 337-354.

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