Surface enrichment of Ir on the IrRu alloy for efficient and stable water oxidation catalysis in acid

Inducing the surface enrichment of active noble metal can not only help to stabilize the catalyst but also modify the catalytic performance of the catalyst through electronic and geometric effects. Herein, we report the in situ surface enrichment of Ir on IrRu alloy during the oxygen evolution reaction (OER). The surface enrichment of Ir was probed by ex situ high-resolution transmission electron microscopy (HRTEM), in situ X-ray absorption spectroscopy (XAS), and electrochemical Cu stripping, leading to complementary characterizations of the dynamic reconstruction of the IrRu alloy during OER. Guided by the density functional theory (DFT), an IrRu alloy with low Ir content (20 wt%) was constructed, which displayed a low overpotential of only 230 mV to deliver an OER current density of 10 mA cm⁻² in 0.1 M HClO₄ solution and maintained stable performance for over 20 h. To investigate the practical application potential, a proton exchange membrane (PEM) water electrolyzer using the IrRu alloy as the anode catalyst was assembled, which required a low cell voltage of only 1.48 V to generate a current density of 1 A cm⁻². © 2022 The Royal Society of Chemistry.