Surface Coordination of Black Phosphorus for Robust Air and Water Stability

Yuetao Zhao; Huaiyu Wang; Hao Huang; Quanlan Xiao; Yanhua Xu; Zhinan Guo; Hanhan Xie; Jundong Shao; Zhengbo Sun; Weijia Han; Xue-Feng Yu; Penghui Li; Paul K. Chu

doi:10.1002/anie.201512038

Surface Coordination of Black Phosphorus for Robust Air and Water Stability

Yuetao Zhao
, Huaiyu Wang^*
, Hao Huang
, Quanlan Xiao
, Yanhua Xu
, Zhinan Guo
, Hanhan Xie
, Jundong Shao
, Zhengbo Sun
, Weijia Han
, Xue-Feng Yu^*
, Penghui Li
, Paul K. Chu^*

^*Corresponding author for this work

Research output: Journal Publications and Reviews › RGC 21 - Publication in refereed journal › peer-review

582 Citations (Scopus)

Abstract

A titanium sulfonate ligand is synthesized for surface coordination of black phosphorus (BP). In contrast to serious degradation observed from the bare BP, the BP after surface coordination exhibits excellent stability during dispersion in water and exposure to air for a long period of time, thereby significantly extending the lifetime and spurring broader application of BP.

Original language	English
Pages (from-to)	5003-5007
Journal	Angewandte Chemie - International Edition
Volume	55
Issue number	16
DOIs	https://doi.org/10.1002/anie.201512038
Publication status	Published - 11 Apr 2016

Research Keywords

black phosphorus
degradation
oxidation
phosphorenes
stability

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title = "Surface Coordination of Black Phosphorus for Robust Air and Water Stability",

abstract = "A titanium sulfonate ligand is synthesized for surface coordination of black phosphorus (BP). In contrast to serious degradation observed from the bare BP, the BP after surface coordination exhibits excellent stability during dispersion in water and exposure to air for a long period of time, thereby significantly extending the lifetime and spurring broader application of BP.",

keywords = "black phosphorus, degradation, oxidation, phosphorenes, stability",

author = "Yuetao Zhao and Huaiyu Wang and Hao Huang and Quanlan Xiao and Yanhua Xu and Zhinan Guo and Hanhan Xie and Jundong Shao and Zhengbo Sun and Weijia Han and Xue-Feng Yu and Penghui Li and Chu, \{Paul K.\}",

year = "2016",

month = apr,

day = "11",

doi = "10.1002/anie.201512038",

language = "English",

volume = "55",

pages = "5003--5007",

journal = "Angewandte Chemie - International Edition",

issn = "1433-7851",

publisher = "John Wiley \& Sons",

number = "16",

}

TY - JOUR

T1 - Surface Coordination of Black Phosphorus for Robust Air and Water Stability

AU - Zhao, Yuetao

AU - Wang, Huaiyu

AU - Huang, Hao

AU - Xiao, Quanlan

AU - Xu, Yanhua

AU - Guo, Zhinan

AU - Xie, Hanhan

AU - Shao, Jundong

AU - Sun, Zhengbo

AU - Han, Weijia

AU - Yu, Xue-Feng

AU - Li, Penghui

AU - Chu, Paul K.

PY - 2016/4/11

Y1 - 2016/4/11

N2 - A titanium sulfonate ligand is synthesized for surface coordination of black phosphorus (BP). In contrast to serious degradation observed from the bare BP, the BP after surface coordination exhibits excellent stability during dispersion in water and exposure to air for a long period of time, thereby significantly extending the lifetime and spurring broader application of BP.

AB - A titanium sulfonate ligand is synthesized for surface coordination of black phosphorus (BP). In contrast to serious degradation observed from the bare BP, the BP after surface coordination exhibits excellent stability during dispersion in water and exposure to air for a long period of time, thereby significantly extending the lifetime and spurring broader application of BP.

KW - black phosphorus

KW - degradation

KW - oxidation

KW - phosphorenes

KW - stability

UR - https://www.scopus.com/pages/publications/84960408290

UR - https://www.scopus.com/record/pubmetrics.uri?eid=2-s2.0-84960408290&origin=recordpage

U2 - 10.1002/anie.201512038

DO - 10.1002/anie.201512038

M3 - RGC 21 - Publication in refereed journal

SN - 1433-7851

VL - 55

SP - 5003

EP - 5007

JO - Angewandte Chemie - International Edition

JF - Angewandte Chemie - International Edition

IS - 16

ER -

Surface Coordination of Black Phosphorus for Robust Air and Water Stability

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