Abstract
Combining in-depth neutron diffraction and systematic bulk studies, we discover that the 5 × 5 Fe vacancy order, with its associated block antiferromagnetic order, is the ground state with varying occupancy ratios of the iron 16i and vacancy 4d sites across the phase-diagram of KxFe2-ySe2 . The orthorhombic order, with one of the four Fe sites vacant, appears only at intermediate temperatures as a competing phase. The material experiences an insulator to metal crossover when the √5 × √5 order is highly developed. Superconductivity occurs in such a metallic phase.
©2013 Chinese Physical Society and IOP Publishing Ltd
©2013 Chinese Physical Society and IOP Publishing Ltd
| Original language | English |
|---|---|
| Article number | 027402 |
| Journal | Chinese Physics Letters |
| Volume | 30 |
| Issue number | 2 |
| DOIs | |
| Publication status | Published - Feb 2013 |
| Externally published | Yes |
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