Study on hydro-liquefaction kinetics of thermal dissolution soluble fraction from Shenfu sub-bituminous coal

Hengfu Shui; Haiyan Xu; Yan Zhou; Tao Shui; Chunxiu Pan; Zhicai Wang; Zhiping Lei; Shibiao Ren; Shigang Kang; Chunbao (Charles) Xu

doi:10.1016/j.fuel.2017.03.048

Study on hydro-liquefaction kinetics of thermal dissolution soluble fraction from Shenfu sub-bituminous coal

Hengfu Shui^*
, Haiyan Xu
, Yan Zhou
, Tao Shui
, Chunxiu Pan
, Zhicai Wang
, Zhiping Lei
, Shibiao Ren
, Shigang Kang
, Chunbao (Charles) Xu

^*Corresponding author for this work

Research output: Journal Publications and Reviews › RGC 21 - Publication in refereed journal › peer-review

25 Citations (Scopus)

Abstract

Thermal dissolution (TD) of coal and hydro-liquefaction of the thermal dissolution soluble fraction (TDSF) with a high activity catalyst is one of effective high efficient hydro-liquefaction of coal techniques. In this study, a Chinese Shenfu (SF) sub-bituminous coal was thermally dissolved, and the TDSF obtained was further hydro-liquefied with Ni–Mo-S/Al₂O₃ catalyst. Based on the hydro-liquefaction results, a model including series and parallel reactions was established for the hydro-liquefaction of TDSF catalyzed by Ni–Mo-S/Al₂O₃, and the regressive reactions were ruled out in the model. From the kinetic parameters calculated, it suggested that the regressive reactions including the char formation reactions were negligible in the hydro-liquefaction of TDSF catalyzed by Ni–Mo-S/Al₂O₃. The reactions of TDSF to preasphaltene and preasphaltene to oil + gas predominated the formation of oil + gas. Ni–Mo-S/Al₂O₃ could decrease the activation energy of preasphaltene to oil + gas reaction, thus promoting the formation of oil and gas in the catalytic hydro-liquefaction of TDSF. © 2017 Elsevier Ltd

Original language	English
Pages (from-to)	576-582
Journal	Fuel
Volume	200
DOIs	https://doi.org/10.1016/j.fuel.2017.03.048
Publication status	Published - 2017
Externally published	Yes

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Publication details (e.g. title, author(s), publication statuses and dates) are captured on an “AS IS” and “AS AVAILABLE” basis at the time of record harvesting from the data source. Suggestions for further amendments or supplementary information can be sent to [email protected].

Research Keywords

Catalyst
Coal
Hydro-liquefaction kinetics
Thermal dissolution soluble fraction

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@article{5921f5eab69c47aba062186e3b59917c,

title = "Study on hydro-liquefaction kinetics of thermal dissolution soluble fraction from Shenfu sub-bituminous coal",

abstract = "Thermal dissolution (TD) of coal and hydro-liquefaction of the thermal dissolution soluble fraction (TDSF) with a high activity catalyst is one of effective high efficient hydro-liquefaction of coal techniques. In this study, a Chinese Shenfu (SF) sub-bituminous coal was thermally dissolved, and the TDSF obtained was further hydro-liquefied with Ni–Mo-S/Al2O3 catalyst. Based on the hydro-liquefaction results, a model including series and parallel reactions was established for the hydro-liquefaction of TDSF catalyzed by Ni–Mo-S/Al2O3, and the regressive reactions were ruled out in the model. From the kinetic parameters calculated, it suggested that the regressive reactions including the char formation reactions were negligible in the hydro-liquefaction of TDSF catalyzed by Ni–Mo-S/Al2O3. The reactions of TDSF to preasphaltene and preasphaltene to oil + gas predominated the formation of oil + gas. Ni–Mo-S/Al2O3 could decrease the activation energy of preasphaltene to oil + gas reaction, thus promoting the formation of oil and gas in the catalytic hydro-liquefaction of TDSF. {\textcopyright} 2017 Elsevier Ltd",

keywords = "Catalyst, Coal, Hydro-liquefaction kinetics, Thermal dissolution soluble fraction",

author = "Hengfu Shui and Haiyan Xu and Yan Zhou and Tao Shui and Chunxiu Pan and Zhicai Wang and Zhiping Lei and Shibiao Ren and Shigang Kang and Xu, \{Chunbao (Charles)\}",

note = "Publication details (e.g. title, author(s), publication statuses and dates) are captured on an “AS IS” and “AS AVAILABLE” basis at the time of record harvesting from the data source. Suggestions for further amendments or supplementary information can be sent to [email protected].",

year = "2017",

doi = "10.1016/j.fuel.2017.03.048",

language = "English",

volume = "200",

pages = "576--582",

journal = "Fuel",

issn = "0016-2361",

publisher = "Elsevier B.V.",

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TY - JOUR

T1 - Study on hydro-liquefaction kinetics of thermal dissolution soluble fraction from Shenfu sub-bituminous coal

AU - Shui, Hengfu

AU - Xu, Haiyan

AU - Zhou, Yan

AU - Shui, Tao

AU - Pan, Chunxiu

AU - Wang, Zhicai

AU - Lei, Zhiping

AU - Ren, Shibiao

AU - Kang, Shigang

AU - Xu, Chunbao (Charles)

N1 - Publication details (e.g. title, author(s), publication statuses and dates) are captured on an “AS IS” and “AS AVAILABLE” basis at the time of record harvesting from the data source. Suggestions for further amendments or supplementary information can be sent to [email protected].

PY - 2017

Y1 - 2017

N2 - Thermal dissolution (TD) of coal and hydro-liquefaction of the thermal dissolution soluble fraction (TDSF) with a high activity catalyst is one of effective high efficient hydro-liquefaction of coal techniques. In this study, a Chinese Shenfu (SF) sub-bituminous coal was thermally dissolved, and the TDSF obtained was further hydro-liquefied with Ni–Mo-S/Al2O3 catalyst. Based on the hydro-liquefaction results, a model including series and parallel reactions was established for the hydro-liquefaction of TDSF catalyzed by Ni–Mo-S/Al2O3, and the regressive reactions were ruled out in the model. From the kinetic parameters calculated, it suggested that the regressive reactions including the char formation reactions were negligible in the hydro-liquefaction of TDSF catalyzed by Ni–Mo-S/Al2O3. The reactions of TDSF to preasphaltene and preasphaltene to oil + gas predominated the formation of oil + gas. Ni–Mo-S/Al2O3 could decrease the activation energy of preasphaltene to oil + gas reaction, thus promoting the formation of oil and gas in the catalytic hydro-liquefaction of TDSF. © 2017 Elsevier Ltd

AB - Thermal dissolution (TD) of coal and hydro-liquefaction of the thermal dissolution soluble fraction (TDSF) with a high activity catalyst is one of effective high efficient hydro-liquefaction of coal techniques. In this study, a Chinese Shenfu (SF) sub-bituminous coal was thermally dissolved, and the TDSF obtained was further hydro-liquefied with Ni–Mo-S/Al2O3 catalyst. Based on the hydro-liquefaction results, a model including series and parallel reactions was established for the hydro-liquefaction of TDSF catalyzed by Ni–Mo-S/Al2O3, and the regressive reactions were ruled out in the model. From the kinetic parameters calculated, it suggested that the regressive reactions including the char formation reactions were negligible in the hydro-liquefaction of TDSF catalyzed by Ni–Mo-S/Al2O3. The reactions of TDSF to preasphaltene and preasphaltene to oil + gas predominated the formation of oil + gas. Ni–Mo-S/Al2O3 could decrease the activation energy of preasphaltene to oil + gas reaction, thus promoting the formation of oil and gas in the catalytic hydro-liquefaction of TDSF. © 2017 Elsevier Ltd

KW - Catalyst

KW - Coal

KW - Hydro-liquefaction kinetics

KW - Thermal dissolution soluble fraction

UR - https://www.scopus.com/pages/publications/85017314716

UR - https://www.scopus.com/record/pubmetrics.uri?eid=2-s2.0-85017314716&origin=recordpage

U2 - 10.1016/j.fuel.2017.03.048

DO - 10.1016/j.fuel.2017.03.048

M3 - RGC 21 - Publication in refereed journal

SN - 0016-2361

VL - 200

SP - 576

EP - 582

JO - Fuel

JF - Fuel

ER -

Study on hydro-liquefaction kinetics of thermal dissolution soluble fraction from Shenfu sub-bituminous coal

Abstract

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Research Keywords

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