Studies on the magnetic property of μ3-oxotriiron(III) complex [Fe3O(OBz)6(CH3OH)3](NO3)(CH3OH)2 (HOBz—Benzoic acid)

Guo-Xiong Wang; Hua Zhang; Yao Chen; Tian-Yang Yao; De-Gang Fu

doi:10.1002/cjoc.19960140303

Author(s)

Guo-Xiong Wang
Hua Zhang
Yao Chen
Tian-Yang Yao
De-Gang Fu

Detail(s)

Original language	English
Pages (from-to)	200-205
Journal / Publication	Chinese Journal of Chemistry
Volume	14
Issue number	3
Online published	1 May 1996
Publication status	Published - May 1996
Externally published	Yes

Link(s)

DOI	DOI https://doi.org/10.1002/cjoc.19960140303 Final Published version
	Check@CityULib
Link to Scopus	https://www.scopus.com/record/display.uri?eid=2-s2.0-1542743835&origin=recordpage
Permanent Link	https://scholars.cityu.edu.hk/en/publications/publication(44e81699-26d8-4271-805c-1159348f1b78).html

Abstract

The magnetic property of μ₃-oxotriiron(III) complex [Fe₃O(OBz)₆(CH₃OH)₃](NP₃)-(CH₃OH)₂ (HOBz—benzoic acid) has been studied. We use isosceles triangle model and molecular field correction to fit the experimental magnetic susceptibility data. It shows that an intramolecular antiferromagnetic exchange interaction occurs with J=-31.27 cm^-1, J '=-27.26 cm^-1, and a weaker intermolecular antiferromagnetic exchange interaction occurs with zJ'=-3.76 cm^-1. We give the d ⁵-d ⁵-d ⁵ energy level diagram of triiron(III) complex as a function of J'/J. From the diagram we can get the total spin S T of the complex as 1/2 in the ground state.

Research Area(s)

μ3-oxotriiron(III) complex, antiferromagnetic exchange, energy level diagram, Magnetic property

Citation Format(s)

[ RIS ] [ BibTeX ]

Studies on the magnetic property of μ₃-oxotriiron(III) complex [Fe₃O(OBz)₆(CH₃OH)₃](NO₃)(CH₃OH)₂ (HOBz—Benzoic acid). / Wang, Guo-Xiong; Zhang, Hua; Chen, Yao et al.
In: Chinese Journal of Chemistry, Vol. 14, No. 3, 05.1996, p. 200-205.

Research output: Journal Publications and Reviews › RGC 21 - Publication in refereed journal › peer-review

Wang, G-X, Zhang, H, Chen, Y, Yao, T-Y & Fu, D-G 1996, 'Studies on the magnetic property of μ₃-oxotriiron(III) complex [Fe₃O(OBz)₆(CH₃OH)₃](NO₃)(CH₃OH)₂ (HOBz—Benzoic acid)', Chinese Journal of Chemistry, vol. 14, no. 3, pp. 200-205. https://doi.org/10.1002/cjoc.19960140303

Wang, G.-X., Zhang, H., Chen, Y., Yao, T.-Y., & Fu, D.-G. (1996). Studies on the magnetic property of μ₃-oxotriiron(III) complex [Fe₃O(OBz)₆(CH₃OH)₃](NO₃)(CH₃OH)₂ (HOBz—Benzoic acid). Chinese Journal of Chemistry, 14(3), 200-205. https://doi.org/10.1002/cjoc.19960140303

Wang GX, Zhang H, Chen Y, Yao TY, Fu DG. Studies on the magnetic property of μ₃-oxotriiron(III) complex [Fe₃O(OBz)₆(CH₃OH)₃](NO₃)(CH₃OH)₂ (HOBz—Benzoic acid). Chinese Journal of Chemistry. 1996 May;14(3):200-205. Epub 1996 May 1. doi: 10.1002/cjoc.19960140303

Wang, Guo-Xiong ; Zhang, Hua ; Chen, Yao et al. / Studies on the magnetic property of μ₃-oxotriiron(III) complex [Fe₃O(OBz)₆(CH₃OH)₃](NO₃)(CH₃OH)₂ (HOBz—Benzoic acid). In: Chinese Journal of Chemistry. 1996 ; Vol. 14, No. 3. pp. 200-205.