Studies of the Synthesis, Structure, and Reactivity of a Tetranuclear Mixed-metal Imido Cluster, (η5-C5H5) WRu3(CO)9(μ-NPh)(C≡CPh)

Yun Chi; Der-Kweng Hwang; Shen-Feng Chen; Ling-Kang Liu

doi:10.1039/C39890001540

Author(s)

Yun Chi
Der-Kweng Hwang
Shen-Feng Chen
Ling-Kang Liu

Detail(s)

Original language	English
Pages (from-to)	1540-1543
Journal / Publication	Journal of the Chemical Society, Chemical Communications
Issue number	20
Publication status	Published - 1989
Externally published	Yes

Link(s)

DOI	DOI https://doi.org/10.1039/C39890001540 Final Published version
	Check@CityULib
Link to Scopus	https://www.scopus.com/record/display.uri?eid=2-s2.0-37049073901&origin=recordpage
Permanent Link	https://scholars.cityu.edu.hk/en/publications/publication(d0a1ed86-b28c-478b-b82b-d0ba23c151fd).html

Abstract

The title complex (η⁵-C₅H₅)WRu₃(CO)₉(μ-NPh)(C≡CPh), containing a bridging imido ligand and a μ₄-η²-acetylide ligand, has been prepared by means of the condensation between (η⁵-C₅H₅)W(CO)₃C≡CPh and Ru₃(CO)₁₀(μ₃-NPh), and its reactions with dihydrogen and disubstituted alkyne ligands are presented; the products have been fully characterized by spectroscopic methods and X-ray diffraction studies for two complexes.

Citation Format(s)

[ RIS ] [ BibTeX ]

Studies of the Synthesis, Structure, and Reactivity of a Tetranuclear Mixed-metal Imido Cluster, (η⁵-C₅H₅) WRu₃(CO)₉(μ-NPh)(C≡CPh). / Chi, Yun; Hwang, Der-Kweng; Chen, Shen-Feng et al.

In: Journal of the Chemical Society, Chemical Communications, No. 20, 1989, p. 1540-1543.

Research output: Journal Publications and Reviews (RGC: 21, 22, 62) › 21_Publication in refereed journal › peer-review

Chi, Y, Hwang, D-K, Chen, S-F & Liu, L-K 1989, 'Studies of the Synthesis, Structure, and Reactivity of a Tetranuclear Mixed-metal Imido Cluster, (η⁵-C₅H₅) WRu₃(CO)₉(μ-NPh)(C≡CPh)', Journal of the Chemical Society, Chemical Communications, no. 20, pp. 1540-1543. https://doi.org/10.1039/C39890001540

Chi, Y., Hwang, D-K., Chen, S-F., & Liu, L-K. (1989). Studies of the Synthesis, Structure, and Reactivity of a Tetranuclear Mixed-metal Imido Cluster, (η⁵-C₅H₅) WRu₃(CO)₉(μ-NPh)(C≡CPh). Journal of the Chemical Society, Chemical Communications, (20), 1540-1543. https://doi.org/10.1039/C39890001540

Chi Y, Hwang D-K, Chen S-F, Liu L-K. Studies of the Synthesis, Structure, and Reactivity of a Tetranuclear Mixed-metal Imido Cluster, (η⁵-C₅H₅) WRu₃(CO)₉(μ-NPh)(C≡CPh). Journal of the Chemical Society, Chemical Communications. 1989;(20):1540-1543. doi: 10.1039/C39890001540

Chi, Yun ; Hwang, Der-Kweng ; Chen, Shen-Feng et al. / Studies of the Synthesis, Structure, and Reactivity of a Tetranuclear Mixed-metal Imido Cluster, (η⁵-C₅H₅) WRu₃(CO)₉(μ-NPh)(C≡CPh). In: Journal of the Chemical Society, Chemical Communications. 1989 ; No. 20. pp. 1540-1543.