Studies of the Synthesis, Structure, and Reactivity of a Tetranuclear Mixed-metal Imido Cluster, (η5-C5H5) WRu3(CO)9(μ-NPh)(C≡CPh)

Research output: Journal Publications and Reviews (RGC: 21, 22, 62)21_Publication in refereed journalpeer-review

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Author(s)

  • Yun Chi
  • Der-Kweng Hwang
  • Shen-Feng Chen
  • Ling-Kang Liu

Detail(s)

Original languageEnglish
Pages (from-to)1540-1543
Journal / PublicationJournal of the Chemical Society, Chemical Communications
Issue number20
Publication statusPublished - 1989
Externally publishedYes

Abstract

The title complex (η5-C5H5)WRu3(CO)9(μ-NPh)(C≡CPh), containing a bridging imido ligand and a μ42-acetylide ligand, has been prepared by means of the condensation between (η5-C5H5)W(CO)3C≡CPh and Ru3(CO)103-NPh), and its reactions with dihydrogen and disubstituted alkyne ligands are presented; the products have been fully characterized by spectroscopic methods and X-ray diffraction studies for two complexes.

Citation Format(s)

Studies of the Synthesis, Structure, and Reactivity of a Tetranuclear Mixed-metal Imido Cluster, (η5-C5H5) WRu3(CO)9(μ-NPh)(C≡CPh). / Chi, Yun; Hwang, Der-Kweng; Chen, Shen-Feng; Liu, Ling-Kang.

In: Journal of the Chemical Society, Chemical Communications, No. 20, 1989, p. 1540-1543.

Research output: Journal Publications and Reviews (RGC: 21, 22, 62)21_Publication in refereed journalpeer-review