Studies of the Synthesis, Structure, and Reactivity of a Tetranuclear Mixed-metal Imido Cluster, (η5-C5H5) WRu3(CO)9(μ-NPh)(C≡CPh)

Yun Chi; Der-Kweng Hwang; Shen-Feng Chen; Ling-Kang Liu

doi:10.1039/C39890001540

Studies of the Synthesis, Structure, and Reactivity of a Tetranuclear Mixed-metal Imido Cluster, (η⁵-C₅H₅) WRu₃(CO)₉(μ-NPh)(C≡CPh)

Yun Chi, Der-Kweng Hwang, Shen-Feng Chen, Ling-Kang Liu

Research output: Journal Publications and Reviews › RGC 21 - Publication in refereed journal › peer-review

26 Citations (Scopus)

Abstract

The title complex (η⁵-C₅H₅)WRu₃(CO)₉(μ-NPh)(C≡CPh), containing a bridging imido ligand and a μ₄-η²-acetylide ligand, has been prepared by means of the condensation between (η⁵-C₅H₅)W(CO)₃C≡CPh and Ru₃(CO)₁₀(μ₃-NPh), and its reactions with dihydrogen and disubstituted alkyne ligands are presented; the products have been fully characterized by spectroscopic methods and X-ray diffraction studies for two complexes.

Original language	English
Pages (from-to)	1540-1543
Journal	Journal of the Chemical Society, Chemical Communications
Issue number	20
DOIs	https://doi.org/10.1039/C39890001540
Publication status	Published - 1989
Externally published	Yes

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@article{d0a1ed86b28c478bb82bd0ba23c151fd,

title = "Studies of the Synthesis, Structure, and Reactivity of a Tetranuclear Mixed-metal Imido Cluster, (η5-C5H5) WRu3(CO)9(μ-NPh)(C≡CPh)",

abstract = "The title complex (η5-C5H5)WRu3(CO)9(μ-NPh)(C≡CPh), containing a bridging imido ligand and a μ4-η2-acetylide ligand, has been prepared by means of the condensation between (η5-C5H5)W(CO)3C≡CPh and Ru3(CO)10(μ3-NPh), and its reactions with dihydrogen and disubstituted alkyne ligands are presented; the products have been fully characterized by spectroscopic methods and X-ray diffraction studies for two complexes.",

author = "Yun Chi and Der-Kweng Hwang and Shen-Feng Chen and Ling-Kang Liu",

year = "1989",

doi = "10.1039/C39890001540",

language = "English",

pages = "1540--1543",

journal = "Journal of the Chemical Society, Chemical Communications",

issn = "0022-4936",

publisher = "Royal Society of Chemistry",

number = "20",

}

Studies of the Synthesis, Structure, and Reactivity of a Tetranuclear Mixed-metal Imido Cluster, (η⁵-C₅H₅) WRu₃(CO)₉(μ-NPh)(C≡CPh). / Chi, Yun; Hwang, Der-Kweng; Chen, Shen-Feng et al.
In: Journal of the Chemical Society, Chemical Communications, No. 20, 1989, p. 1540-1543.

Research output: Journal Publications and Reviews › RGC 21 - Publication in refereed journal › peer-review

TY - JOUR

T1 - Studies of the Synthesis, Structure, and Reactivity of a Tetranuclear Mixed-metal Imido Cluster, (η5-C5H5) WRu3(CO)9(μ-NPh)(C≡CPh)

AU - Chi, Yun

AU - Hwang, Der-Kweng

AU - Chen, Shen-Feng

AU - Liu, Ling-Kang

PY - 1989

Y1 - 1989

N2 - The title complex (η5-C5H5)WRu3(CO)9(μ-NPh)(C≡CPh), containing a bridging imido ligand and a μ4-η2-acetylide ligand, has been prepared by means of the condensation between (η5-C5H5)W(CO)3C≡CPh and Ru3(CO)10(μ3-NPh), and its reactions with dihydrogen and disubstituted alkyne ligands are presented; the products have been fully characterized by spectroscopic methods and X-ray diffraction studies for two complexes.

AB - The title complex (η5-C5H5)WRu3(CO)9(μ-NPh)(C≡CPh), containing a bridging imido ligand and a μ4-η2-acetylide ligand, has been prepared by means of the condensation between (η5-C5H5)W(CO)3C≡CPh and Ru3(CO)10(μ3-NPh), and its reactions with dihydrogen and disubstituted alkyne ligands are presented; the products have been fully characterized by spectroscopic methods and X-ray diffraction studies for two complexes.

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U2 - 10.1039/C39890001540

DO - 10.1039/C39890001540

M3 - RGC 21 - Publication in refereed journal

SN - 0022-4936

SP - 1540

EP - 1543

JO - Journal of the Chemical Society, Chemical Communications

JF - Journal of the Chemical Society, Chemical Communications

IS - 20

ER -