Structure and reactivity of a seven-coordinate ruthenium acylperoxo complex

Rui Wang; Yunling Pan; Sushan Feng; Chenyi Liang; Jianhui Xie; Tai-Chu Lau; Yingying Liu

doi:10.1039/d3cc04751b

Structure and reactivity of a seven-coordinate ruthenium acylperoxo complex

Rui Wang
, Yunling Pan
, Sushan Feng
, Chenyi Liang
, Jianhui Xie
, Tai-Chu Lau
, Yingying Liu^*

^*Corresponding author for this work

Department of Chemistry

Research output: Journal Publications and Reviews › RGC 21 - Publication in refereed journal › peer-review

Abstract

The use of metal-acylperoxo complexes as oxidants has been little explored. Herein we report the synthesis and characterization of the first seven-coordinate Ru-acylperoxo complex, [Ru^IV(bdpm)(pic)₂(mCPBA)]⁺ (H₂bdpm = [2,2′-bipyridine]-6,6′-diylbis(diphenylmethanol); pic = 4-picoline; HmCPBA = m-chloroperbenzoic acid). This complex is a highly reactive oxidant for C-H bond activation and O-atom transfer reactions. © The Royal Society of Chemistry 2024.

Original language	English
Pages (from-to)	312–315
Journal	Chemical Communications
Volume	60
Issue number	3
Online published	5 Dec 2023
DOIs	https://doi.org/10.1039/d3cc04751b
Publication status	Published - 11 Jan 2024

Funding

This work is supported by the National Natural Science Foundation of China (22001253).

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title = "Structure and reactivity of a seven-coordinate ruthenium acylperoxo complex",

abstract = "The use of metal-acylperoxo complexes as oxidants has been little explored. Herein we report the synthesis and characterization of the first seven-coordinate Ru-acylperoxo complex, [RuIV(bdpm)(pic)2(mCPBA)]+ (H2bdpm = [2,2′-bipyridine]-6,6′-diylbis(diphenylmethanol); pic = 4-picoline; HmCPBA = m-chloroperbenzoic acid). This complex is a highly reactive oxidant for C-H bond activation and O-atom transfer reactions. {\textcopyright} The Royal Society of Chemistry 2024.",

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T1 - Structure and reactivity of a seven-coordinate ruthenium acylperoxo complex

AU - Wang, Rui

AU - Pan, Yunling

AU - Feng, Sushan

AU - Liang, Chenyi

AU - Xie, Jianhui

AU - Lau, Tai-Chu

AU - Liu, Yingying

PY - 2024/1/11

Y1 - 2024/1/11

N2 - The use of metal-acylperoxo complexes as oxidants has been little explored. Herein we report the synthesis and characterization of the first seven-coordinate Ru-acylperoxo complex, [RuIV(bdpm)(pic)2(mCPBA)]+ (H2bdpm = [2,2′-bipyridine]-6,6′-diylbis(diphenylmethanol); pic = 4-picoline; HmCPBA = m-chloroperbenzoic acid). This complex is a highly reactive oxidant for C-H bond activation and O-atom transfer reactions. © The Royal Society of Chemistry 2024.

AB - The use of metal-acylperoxo complexes as oxidants has been little explored. Herein we report the synthesis and characterization of the first seven-coordinate Ru-acylperoxo complex, [RuIV(bdpm)(pic)2(mCPBA)]+ (H2bdpm = [2,2′-bipyridine]-6,6′-diylbis(diphenylmethanol); pic = 4-picoline; HmCPBA = m-chloroperbenzoic acid). This complex is a highly reactive oxidant for C-H bond activation and O-atom transfer reactions. © The Royal Society of Chemistry 2024.

UR - https://www.scopus.com/pages/publications/85179613097

UR - https://www.scopus.com/record/pubmetrics.uri?eid=2-s2.0-85179613097&origin=recordpage

U2 - 10.1039/d3cc04751b

DO - 10.1039/d3cc04751b

M3 - RGC 21 - Publication in refereed journal

SN - 1359-7345

VL - 60

SP - 312

EP - 315

JO - Chemical Communications

JF - Chemical Communications

IS - 3

ER -

Structure and reactivity of a seven-coordinate ruthenium acylperoxo complex

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