Structural evaluation of 6-(10-mercaptodecoxyl) quinoline self-assembled monolayer on gold by reflectance absorption infrared spectroscopy

Hao-Li Zhang; Hua Zhang; Jin Zhang; Hu-Lin Li; Zhong-Fan Liu

doi:10.1016/S0928-4931(99)00021-1

Structural evaluation of 6-(10-mercaptodecoxyl) quinoline self-assembled monolayer on gold by reflectance absorption infrared spectroscopy

Hao-Li Zhang, Hua Zhang, Jin Zhang, Hu-Lin Li, Zhong-Fan Liu

Research output: Journal Publications and Reviews › RGC 21 - Publication in refereed journal › peer-review

4 Citations (Scopus)

Abstract

Self-assembled monolayer (SAM) of 6-(10-mercaptodecaoxyl)quinoline (MDQ) on gold was characterized by reflectance absorption infrared spectroscopy (RA-IR). The molecular orientation of MDQ in the SAM was totally evaluated by comparing the RA-IR spectrum of the SAM with a transmission spectrum of a KBr pellet. It was found that the alkyl chain exhibit a tilting angle of 24±5° and a twisting angle of 50±5°. The results suggested that the quinoline moieties in the SAM form an order layer upon the hydrocarbon chain and do not disturb the packing of the alkyl chains obviously. ©1999 Elsevier Science S.A. All rights reserved.

Original language	English
Pages (from-to)	187-190
Journal	Materials Science and Engineering C
Volume	8-9
DOIs	https://doi.org/10.1016/S0928-4931(99)00021-1
Publication status	Published - 1 Dec 1999
Externally published	Yes

Research Keywords

Quinoline derivative
Reflectance absorption infrared spectroscopy (RA-IR)
Self-assembled monolayer (SAM)

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10.1016/S0928-4931(99)00021-1

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title = "Structural evaluation of 6-(10-mercaptodecoxyl) quinoline self-assembled monolayer on gold by reflectance absorption infrared spectroscopy",

abstract = "Self-assembled monolayer (SAM) of 6-(10-mercaptodecaoxyl)quinoline (MDQ) on gold was characterized by reflectance absorption infrared spectroscopy (RA-IR). The molecular orientation of MDQ in the SAM was totally evaluated by comparing the RA-IR spectrum of the SAM with a transmission spectrum of a KBr pellet. It was found that the alkyl chain exhibit a tilting angle of 24±5° and a twisting angle of 50±5°. The results suggested that the quinoline moieties in the SAM form an order layer upon the hydrocarbon chain and do not disturb the packing of the alkyl chains obviously. {\textcopyright}1999 Elsevier Science S.A. All rights reserved.",

keywords = "Quinoline derivative, Reflectance absorption infrared spectroscopy (RA-IR), Self-assembled monolayer (SAM)",

author = "Hao-Li Zhang and Hua Zhang and Jin Zhang and Hu-Lin Li and Zhong-Fan Liu",

year = "1999",

month = dec,

day = "1",

doi = "10.1016/S0928-4931(99)00021-1",

language = "English",

volume = "8-9",

pages = "187--190",

journal = "Materials Science and Engineering C",

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publisher = "Elsevier B.V.",

}

Structural evaluation of 6-(10-mercaptodecoxyl) quinoline self-assembled monolayer on gold by reflectance absorption infrared spectroscopy. / Zhang, Hao-Li; Zhang, Hua; Zhang, Jin et al.
In: Materials Science and Engineering C, Vol. 8-9, 01.12.1999, p. 187-190.

Research output: Journal Publications and Reviews › RGC 21 - Publication in refereed journal › peer-review

TY - JOUR

T1 - Structural evaluation of 6-(10-mercaptodecoxyl) quinoline self-assembled monolayer on gold by reflectance absorption infrared spectroscopy

AU - Zhang, Hao-Li

AU - Zhang, Hua

AU - Zhang, Jin

AU - Li, Hu-Lin

AU - Liu, Zhong-Fan

PY - 1999/12/1

Y1 - 1999/12/1

N2 - Self-assembled monolayer (SAM) of 6-(10-mercaptodecaoxyl)quinoline (MDQ) on gold was characterized by reflectance absorption infrared spectroscopy (RA-IR). The molecular orientation of MDQ in the SAM was totally evaluated by comparing the RA-IR spectrum of the SAM with a transmission spectrum of a KBr pellet. It was found that the alkyl chain exhibit a tilting angle of 24±5° and a twisting angle of 50±5°. The results suggested that the quinoline moieties in the SAM form an order layer upon the hydrocarbon chain and do not disturb the packing of the alkyl chains obviously. ©1999 Elsevier Science S.A. All rights reserved.

AB - Self-assembled monolayer (SAM) of 6-(10-mercaptodecaoxyl)quinoline (MDQ) on gold was characterized by reflectance absorption infrared spectroscopy (RA-IR). The molecular orientation of MDQ in the SAM was totally evaluated by comparing the RA-IR spectrum of the SAM with a transmission spectrum of a KBr pellet. It was found that the alkyl chain exhibit a tilting angle of 24±5° and a twisting angle of 50±5°. The results suggested that the quinoline moieties in the SAM form an order layer upon the hydrocarbon chain and do not disturb the packing of the alkyl chains obviously. ©1999 Elsevier Science S.A. All rights reserved.

KW - Quinoline derivative

KW - Reflectance absorption infrared spectroscopy (RA-IR)

KW - Self-assembled monolayer (SAM)

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UR - https://www.scopus.com/record/pubmetrics.uri?eid=2-s2.0-0039763528&origin=recordpage

U2 - 10.1016/S0928-4931(99)00021-1

DO - 10.1016/S0928-4931(99)00021-1

M3 - RGC 21 - Publication in refereed journal

SN - 0928-4931

VL - 8-9

SP - 187

EP - 190

JO - Materials Science and Engineering C

JF - Materials Science and Engineering C

ER -

Structural evaluation of 6-(10-mercaptodecoxyl) quinoline self-assembled monolayer on gold by reflectance absorption infrared spectroscopy

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Research Keywords

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