Structural and mechanistic studies of co-ordination compounds. Part 37. Ligand-substitution kinetics of some halogeno tetra-amine complexes of cobalt(III), ruthenium(II), and ruthenium(III)

Research output: Journal Publications and Reviews › RGC 22 - Publication in policy or professional journal

Overview

7 Scopus Citations

View graph of relations

Author(s)

Chung-Kwong Poon
Tai-Chu Lau
Chung-Lai Wong
Yan-Ping Kan

Detail(s)

Original language	English
Pages (from-to)	1641-1645
Journal / Publication	Journal of the Chemical Society, Dalton Transactions
Issue number	8
Publication status	Published - 1983
Externally published	Yes

Link(s)

DOI	DOI https://doi.org/10.1039/DT9830001641 Final Published version
	Check@CityULib
Link to Scopus	https://www.scopus.com/record/display.uri?eid=2-s2.0-37049108030&origin=recordpage
Permanent Link	https://scholars.cityu.edu.hk/en/publications/publication(600c509f-79aa-4c16-b163-1a50f3097ed7).html

Abstract

The first-order rate constants for the replacement of X^- from 21 different complexes of the type trans-[ML(A)X]ⁿ⁺ [M = Co^III, Ru^III, or Ru^II; L = either two bidentate or one quadridentate amine ligand; and (A)X = (Cl)Cl, (Cl)Br, (Br)Cl, or (Br)Br] have been determined over a range of temperature. It has been found that the ruthenium(II) (d⁶) complexes behave much more like the corresponding ruthenium(III) (d⁵) than the cobalt(III) (d⁶) and rhodium(III) (d⁶) systems.

Fingerprint

Publication fingerprints text

Ruthenium Chemistry

Cobalt Chemistry

Coordination Compou... Chemistry

Mechanistic Study Chemistry

Rhodium Chemistry

Rate Constant Chemistry

Full Fingerprint ›

Citation Format(s)

[ RIS ] [ BibTeX ]

Structural and mechanistic studies of co-ordination compounds. Part 37. Ligand-substitution kinetics of some halogeno tetra-amine complexes of cobalt(III), ruthenium(II), and ruthenium(III). / Poon, Chung-Kwong; Lau, Tai-Chu; Wong, Chung-Lai et al.
In: Journal of the Chemical Society, Dalton Transactions, No. 8, 1983, p. 1641-1645.

Research output: Journal Publications and Reviews › RGC 22 - Publication in policy or professional journal

Poon, C-K, Lau, T-C, Wong, C-L & Kan, Y-P 1983, 'Structural and mechanistic studies of co-ordination compounds. Part 37. Ligand-substitution kinetics of some halogeno tetra-amine complexes of cobalt(III), ruthenium(II), and ruthenium(III)', Journal of the Chemical Society, Dalton Transactions, no. 8, pp. 1641-1645. https://doi.org/10.1039/DT9830001641

Poon, C.-K., Lau, T.-C., Wong, C.-L., & Kan, Y.-P. (1983). Structural and mechanistic studies of co-ordination compounds. Part 37. Ligand-substitution kinetics of some halogeno tetra-amine complexes of cobalt(III), ruthenium(II), and ruthenium(III). Journal of the Chemical Society, Dalton Transactions, (8), 1641-1645. https://doi.org/10.1039/DT9830001641

Poon CK, Lau TC, Wong CL, Kan YP. Structural and mechanistic studies of co-ordination compounds. Part 37. Ligand-substitution kinetics of some halogeno tetra-amine complexes of cobalt(III), ruthenium(II), and ruthenium(III). Journal of the Chemical Society, Dalton Transactions. 1983;(8):1641-1645. doi: 10.1039/DT9830001641

Poon, Chung-Kwong ; Lau, Tai-Chu ; Wong, Chung-Lai et al. / Structural and mechanistic studies of co-ordination compounds. Part 37. Ligand-substitution kinetics of some halogeno tetra-amine complexes of cobalt(III), ruthenium(II), and ruthenium(III). In: Journal of the Chemical Society, Dalton Transactions. 1983 ; No. 8. pp. 1641-1645.