Stereoselective formation of a single-stranded helicate : Structure of a bis(palladium-allyl)quaterpyridine complex and its use in catalytic enantioselective allylic substitution
Research output: Journal Publications and Reviews (RGC: 21, 22, 62) › 21_Publication in refereed journal › peer-review
Author(s)
Detail(s)
| Original language | English |
|---|---|
| Pages (from-to) | 4841-4843 |
| Journal / Publication | Chemical Communications |
| Issue number | 46 |
| Publication status | Published - 2006 |
Link(s)
Abstract
Chiral C2-symmetric quaterpyridine L reacts with [Pd(η3-C3H5)Cl]2 to form a chiral single-stranded helical binuclear palladium complex of formula [Pd 2(η3-C3H5)2(L)] 2+; the complex can efficiently catalyze allylic substitution of 1,3-diphenylprop-2-enyl acetate with dimethyl malonate with enantioselectivity up to 85%. © The Royal Society of Chemistry 2006.
Citation Format(s)
Stereoselective formation of a single-stranded helicate : Structure of a bis(palladium-allyl)quaterpyridine complex and its use in catalytic enantioselective allylic substitution. / Kwong, Hoi-Lun; Yeung, Ho-Lun; Lee, Wing-Sze et al.
In: Chemical Communications, No. 46, 2006, p. 4841-4843.Research output: Journal Publications and Reviews (RGC: 21, 22, 62) › 21_Publication in refereed journal › peer-review
