Stereoelectronic Properties, Stereospecificity and Stabilization of α‐Seleno Carbanions. An ab initio Study
Research output: Journal Publications and Reviews › RGC 21 - Publication in refereed journal › peer-review
Author(s)
Detail(s)
| Original language | English |
|---|---|
| Pages (from-to) | 1239-1246 |
| Journal / Publication | Helvetica Chimica Acta |
| Volume | 60 |
| Issue number | 4 |
| Publication status | Published - 1 Jun 1977 |
| Externally published | Yes |
Link(s)
Abstract
An ab initio study of α‐seleno carbanions show that they are subject to appreciable polarization and stereoelectronic effects. Like in α‐thia carbanions, the equatorial e forms are more stable than the axial a forms, one of the stabilizing contributions being the conformation dependent (C‐lone pair, σ* SeZ) interaction. The carbanion stabilizing effect of the α‐Se atom is about 3 kcal/mol larger than that of the sulfur analog. As in the case of the sulfur no specific effect of the d orbitals is found. Copyright © 1977 Verlag GmbH & Co. KGaA, Weinheim
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Citation Format(s)
Stereoelectronic Properties, Stereospecificity and Stabilization of α‐Seleno Carbanions. An ab initio Study. / Lehn, Jean‐Marie; Wipff, Georges; Demuynck, Jean.
In: Helvetica Chimica Acta, Vol. 60, No. 4, 01.06.1977, p. 1239-1246.
In: Helvetica Chimica Acta, Vol. 60, No. 4, 01.06.1977, p. 1239-1246.
Research output: Journal Publications and Reviews › RGC 21 - Publication in refereed journal › peer-review
