Stabilizing Liquids Using Interfacial Supramolecular Assemblies

Peiyang Gu; Xiaobo Luo; Shiyuan Zhou; Danfeng Wang; Zhongyu Li; Yu Chai; Yuzhe Zhang; Shaowei Shi; Thomas P. Russell

doi:10.1002/anie.202303789

Stabilizing Liquids Using Interfacial Supramolecular Assemblies

Peiyang Gu, Xiaobo Luo, Shiyuan Zhou, Danfeng Wang, Zhongyu Li, Yu Chai, Yuzhe Zhang, Shaowei Shi, Thomas P. Russell

Department of Physics

Research output: Journal Publications and Reviews › RGC 21 - Publication in refereed journal › peer-review

22 Citations (Scopus)

Abstract

Stabilizing liquids based on supramolecular assembly (non-covalent intermolecular interactions) has attracted significant interest, due to the increasing demand for soft, liquid-based devices where the shape of the liquid is far from the equilibrium spherical shape. The components comprising these interfacial assemblies must have sufficient binding energies to the interface to prevent their ejection from the interface when the assemblies are compressed. Here, we highlight recent advances in structuring liquids based on non-covalent intermolecular interactions. We describe some of the progress made that reveals structure-property relationships. In addition to treating advances, we discuss some of the limitations and provide a perspective on future directions to inspire further studies on structured liquids based on supramolecular assembly.

Original language	English
Article number	e202303789
Journal	Angewandte Chemie (International Edition)
Online published	13 Jun 2023
DOIs	https://doi.org/10.1002/anie.202303789
Publication status	Online published - 13 Jun 2023

Funding

This work was supported by the U.S. Department of Energy, Office of Science, Office of Basic Energy Sciences, Materials Sciences and Engineering Division under Contract No. DE-AC02-05-CH11231 within the Adaptive Interfacial Assemblies Towards Structuring Liquids program (KCTR16). Y.C. thanks the financial support from the Research Grants Council of Hong Kong (Project No. 21304421). P.G. thanks Changzhou Introduction Program of Innovative Leading Talents (CQ20220111) and the financial support from the National Natural Science Foundation of China (51803143).

Research Keywords

Interfacial Assemblies
Non-Covalent Intermolecular Interactions
Stabilizing Liquids
Structuring Liquids
Supramolecular Assembly
PI-PI STACKING
NANOPARTICLE SURFACTANTS
NONEQUILIBRIUM SHAPES
STRUCTURED LIQUIDS
POLYMERIZATION
WATER
POLYMERS
DRIVEN
DROPS
GELS

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RGC-funded

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10.1002/anie.202303789

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author = "Peiyang Gu and Xiaobo Luo and Shiyuan Zhou and Danfeng Wang and Zhongyu Li and Yu Chai and Yuzhe Zhang and Shaowei Shi and Russell, {Thomas P.}",

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AU - Gu, Peiyang

AU - Luo, Xiaobo

AU - Zhou, Shiyuan

AU - Wang, Danfeng

AU - Li, Zhongyu

AU - Chai, Yu

AU - Zhang, Yuzhe

AU - Shi, Shaowei

AU - Russell, Thomas P.

PY - 2023/6/13

Y1 - 2023/6/13

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KW - Non-Covalent Intermolecular Interactions

KW - Stabilizing Liquids

KW - Structuring Liquids

KW - Supramolecular Assembly

KW - PI-PI STACKING

KW - NANOPARTICLE SURFACTANTS

KW - NONEQUILIBRIUM SHAPES

KW - STRUCTURED LIQUIDS

KW - POLYMERIZATION

KW - WATER

KW - POLYMERS

KW - DRIVEN

KW - DROPS

KW - GELS

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ER -

Stabilizing Liquids Using Interfacial Supramolecular Assemblies

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Research Keywords

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ECS: In-situ Atomic Force Microscopy Study of the Nanoparticle Self-assembly at the Liquid Interface

Cite this

Stabilizing Liquids Using Interfacial Supramolecular Assemblies

Abstract

Funding

Research Keywords

RGC Funding Information

Access Output

Other Access Options

Permanent Link

Other Files and Links

Fingerprint

Projects

ECS: In-situ Atomic Force Microscopy Study of the Nanoparticle Self-assembly at the Liquid Interface

Cite this