Speleands. Macropolycyclic receptor cages based on binding and shaping sub‐units. Synthesis and properties of macrocycle cyclotriveratrylene combinations. Preliminary communication
Research output: Journal Publications and Reviews › RGC 21 - Publication in refereed journal › peer-review
Author(s)
Detail(s)
| Original language | English |
|---|---|
| Pages (from-to) | 1894-1897 |
| Journal / Publication | Helvetica Chimica Acta |
| Volume | 65 |
| Issue number | 6 |
| Publication status | Published - 22 Sept 1982 |
| Externally published | Yes |
Link(s)
Abstract
Combination of a receptor unit with a rigid shaping unit produces a new type of receptor molecules of the cryptand class, hollow macropolycyclic molecules termed speleands, capable of substrate inclusion. Two members of this category of compounds 1 and 2, have been synthesized by connecting in a single step, a macro‐cyclic [18]‐N<sub>3</sub>O<sub>3</sub> binding unit with a rigid cyclotriveratrylene unit via three bridges. Compound 1 binds the rnethylammonium cation forming both external and internal complexes; for the latter a ‘speleme’ structure, schematically represented by 15, may be proposed. Copyright © 1982 Verlag GmbH & Co. KGaA, Weinheim
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Citation Format(s)
Speleands. Macropolycyclic receptor cages based on binding and shaping sub‐units. Synthesis and properties of macrocycle cyclotriveratrylene combinations. Preliminary communication. / Canceill, Josette; Collet, André; Gabard, Jacqueline et al.
In: Helvetica Chimica Acta, Vol. 65, No. 6, 22.09.1982, p. 1894-1897.
In: Helvetica Chimica Acta, Vol. 65, No. 6, 22.09.1982, p. 1894-1897.
Research output: Journal Publications and Reviews › RGC 21 - Publication in refereed journal › peer-review
