Spectroscopic properties and redox chemistry of the phosphorescent excited state of [Au2(dppm)2]2+ [dppm = bis(diphenylphosphino)methane]
Research output: Journal Publications and Reviews (RGC: 21, 22, 62) › 22_Publication in policy or professional journal
Author(s)
Detail(s)
Original language | English |
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Pages (from-to) | 885-886 |
Journal / Publication | Journal of the Chemical Society, Chemical Communications |
Issue number | 13 |
Publication status | Published - 1989 |
Link(s)
Abstract
The complex [Au2(dppm)2]2+ [dppm = bis(diphenylphosphino)methane] exhibits a long-lived room temperature photoluminescence in fluid solutions (emission maximum, 565 nm; τ0, 17.0 μs; Φem, 0.15); the phosphorescent excited state of [Au2(dppm)2]2+ undergoes oxidative and reductive quenching with methyl viologen and N,N,N′, N′-tetramethyl-p-phenylenediamine, respectively, and can be quenched by organic halides.
Citation Format(s)
Spectroscopic properties and redox chemistry of the phosphorescent excited state of [Au2(dppm)2]2+ [dppm = bis(diphenylphosphino)methane]. / Che, Chi-Ming; Kwong, Hoi-Lun; Yam, Vivian Wing-Wah et al.
In: Journal of the Chemical Society, Chemical Communications, No. 13, 1989, p. 885-886.Research output: Journal Publications and Reviews (RGC: 21, 22, 62) › 22_Publication in policy or professional journal