Solvothermal syntheses of three new one-dimensional ternary selenidostannates: [DBNH][M1/2Sn1/2Se2] (M = Mn, Zn, Hg)

Wei-Wei Xiong; Pei-Zhou Li; Tian-Hua Zhou; Yanli Zhao; Rong Xu; Qichun Zhang

doi:10.1016/j.jssc.2013.05.023

Solvothermal syntheses of three new one-dimensional ternary selenidostannates: [DBNH][M_1/2Sn_1/2Se₂] (M = Mn, Zn, Hg)

Wei-Wei Xiong
, Pei-Zhou Li
, Tian-Hua Zhou
, Yanli Zhao
, Rong Xu
, Qichun Zhang^*

^*Corresponding author for this work

Research output: Journal Publications and Reviews › RGC 21 - Publication in refereed journal › peer-review

12 Citations (Scopus)

Abstract

Three new ternary selenidostannates [DBNH][M_1/2Sn _1/2Se₂] (M = Mn (1), Zn (2), Hg (3); DBN = 1,5-diazabicyclo[4.3.0]non-5-ene) have been synthesized under solvothermal condition. Single crystal X-ray analyses reveal that compounds 1-3 crystallize in the tetragonal space group P4₂/ncm. The structures of 1-3 feature a similar straight one-dimensional [M_1/2Sn_1/2Se ₂]n^n- chain, which is built up by edge-sharing M _1/2Sn_1/2Se₄ tetrahedra. The transition metal ions (e.g. Mn²⁺ (1), Zn²⁺ (2), Hg²⁺ (3)) and Sn⁴⁺ ions are located at the same metal site in a mixed-metal phase with a ratio of 0.5/0.5. The band gaps of compounds 2 (2.42 eV) and 3 (2.46 eV) were calculated from the solid state UV-vis diffuse reflectance spectroscopy. © 2013 Elsevier Inc.

Original language	English
Pages (from-to)	86-90
Journal	Journal of Solid State Chemistry
Volume	204
Online published	28 May 2013
DOIs	https://doi.org/10.1016/j.jssc.2013.05.023
Publication status	Published - Aug 2013
Externally published	Yes

Research Keywords

Chalcogenides
Crystal structure
Mixed-metal phase
Ternary

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10.1016/j.jssc.2013.05.023

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title = "Solvothermal syntheses of three new one-dimensional ternary selenidostannates: [DBNH][M1/2Sn1/2Se2] (M = Mn, Zn, Hg)",

abstract = "Three new ternary selenidostannates [DBNH][M1/2Sn 1/2Se2] (M = Mn (1), Zn (2), Hg (3); DBN = 1,5-diazabicyclo[4.3.0]non-5-ene) have been synthesized under solvothermal condition. Single crystal X-ray analyses reveal that compounds 1-3 crystallize in the tetragonal space group P42/ncm. The structures of 1-3 feature a similar straight one-dimensional [M1/2Sn1/2Se 2]nn- chain, which is built up by edge-sharing M 1/2Sn1/2Se4 tetrahedra. The transition metal ions (e.g. Mn2+ (1), Zn2+ (2), Hg2+ (3)) and Sn4+ ions are located at the same metal site in a mixed-metal phase with a ratio of 0.5/0.5. The band gaps of compounds 2 (2.42 eV) and 3 (2.46 eV) were calculated from the solid state UV-vis diffuse reflectance spectroscopy. {\textcopyright} 2013 Elsevier Inc.",

keywords = "Chalcogenides, Crystal structure, Mixed-metal phase, Ternary, Chalcogenides, Crystal structure, Mixed-metal phase, Ternary, Chalcogenides, Crystal structure, Mixed-metal phase, Ternary",

author = "Wei-Wei Xiong and Pei-Zhou Li and Tian-Hua Zhou and Yanli Zhao and Rong Xu and Qichun Zhang",

year = "2013",

month = aug,

doi = "10.1016/j.jssc.2013.05.023",

language = "English",

volume = "204",

pages = "86--90",

journal = "Journal of Solid State Chemistry",

issn = "0022-4596",

publisher = "Academic Press Inc.",

}

TY - JOUR

T1 - Solvothermal syntheses of three new one-dimensional ternary selenidostannates

T2 - [DBNH][M1/2Sn1/2Se2] (M = Mn, Zn, Hg)

AU - Xiong, Wei-Wei

AU - Li, Pei-Zhou

AU - Zhou, Tian-Hua

AU - Zhao, Yanli

AU - Xu, Rong

AU - Zhang, Qichun

PY - 2013/8

Y1 - 2013/8

N2 - Three new ternary selenidostannates [DBNH][M1/2Sn 1/2Se2] (M = Mn (1), Zn (2), Hg (3); DBN = 1,5-diazabicyclo[4.3.0]non-5-ene) have been synthesized under solvothermal condition. Single crystal X-ray analyses reveal that compounds 1-3 crystallize in the tetragonal space group P42/ncm. The structures of 1-3 feature a similar straight one-dimensional [M1/2Sn1/2Se 2]nn- chain, which is built up by edge-sharing M 1/2Sn1/2Se4 tetrahedra. The transition metal ions (e.g. Mn2+ (1), Zn2+ (2), Hg2+ (3)) and Sn4+ ions are located at the same metal site in a mixed-metal phase with a ratio of 0.5/0.5. The band gaps of compounds 2 (2.42 eV) and 3 (2.46 eV) were calculated from the solid state UV-vis diffuse reflectance spectroscopy. © 2013 Elsevier Inc.

AB - Three new ternary selenidostannates [DBNH][M1/2Sn 1/2Se2] (M = Mn (1), Zn (2), Hg (3); DBN = 1,5-diazabicyclo[4.3.0]non-5-ene) have been synthesized under solvothermal condition. Single crystal X-ray analyses reveal that compounds 1-3 crystallize in the tetragonal space group P42/ncm. The structures of 1-3 feature a similar straight one-dimensional [M1/2Sn1/2Se 2]nn- chain, which is built up by edge-sharing M 1/2Sn1/2Se4 tetrahedra. The transition metal ions (e.g. Mn2+ (1), Zn2+ (2), Hg2+ (3)) and Sn4+ ions are located at the same metal site in a mixed-metal phase with a ratio of 0.5/0.5. The band gaps of compounds 2 (2.42 eV) and 3 (2.46 eV) were calculated from the solid state UV-vis diffuse reflectance spectroscopy. © 2013 Elsevier Inc.

KW - Chalcogenides

KW - Crystal structure

KW - Mixed-metal phase

KW - Ternary

KW - Chalcogenides

KW - Crystal structure

KW - Mixed-metal phase

KW - Ternary

KW - Chalcogenides

KW - Crystal structure

KW - Mixed-metal phase

KW - Ternary

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U2 - 10.1016/j.jssc.2013.05.023

DO - 10.1016/j.jssc.2013.05.023

M3 - RGC 21 - Publication in refereed journal

SN - 0022-4596

VL - 204

SP - 86

EP - 90

JO - Journal of Solid State Chemistry

JF - Journal of Solid State Chemistry

ER -

Solvothermal syntheses of three new one-dimensional ternary selenidostannates: [DBNH][M_1/2Sn_1/2Se₂] (M = Mn, Zn, Hg)

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