Solution structures of cobalt-rhodium clusters: The identification of a new hexanuclear cobalt-rhodium species

Mary-Ann Pearsall; István T. Horváth

doi:10.1016/0020-1693(94)04210-1

Solution structures of cobalt-rhodium clusters: The identification of a new hexanuclear cobalt-rhodium species

Mary-Ann Pearsall, István T. Horváth

Research output: Journal Publications and Reviews › RGC 21 - Publication in refereed journal › peer-review

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Abstract

The thermolysis of Co₂Rh₂(CO)₁₂ leads to the quantitative formation of Co₃Rh₃(CO)₁₆. The solution structures of these clusters have been established by IR and low temperature ¹³C NMR spectroscopy. Co₃Rh₃(CO)₁₆ reacts with carbon monoxide at moderate pressure to give the equilibrium mixture of Co₂Rh₂(CO)₁₂ and CoRh(CO)₇. © 1994.

Original language	English
Pages (from-to)	187-189
Journal	Inorganica Chimica Acta
Volume	227
Issue number	2
DOIs	https://doi.org/10.1016/0020-1693(94)04210-1
Publication status	Published - 15 Dec 1994
Externally published	Yes

Research Keywords

Cobalt
Mixed-metal carbonyl clusters
Rhodium

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title = "Solution structures of cobalt-rhodium clusters: The identification of a new hexanuclear cobalt-rhodium species",

abstract = "The thermolysis of Co2Rh2(CO)12 leads to the quantitative formation of Co3Rh3(CO)16. The solution structures of these clusters have been established by IR and low temperature 13C NMR spectroscopy. Co3Rh3(CO)16 reacts with carbon monoxide at moderate pressure to give the equilibrium mixture of Co2Rh2(CO)12 and CoRh(CO)7. {\textcopyright} 1994.",

keywords = "Cobalt, Mixed-metal carbonyl clusters, Rhodium",

author = "Mary-Ann Pearsall and Horv{\'a}th, {Istv{\'a}n T.}",

year = "1994",

month = dec,

day = "15",

doi = "10.1016/0020-1693(94)04210-1",

language = "English",

volume = "227",

pages = "187--189",

journal = "Inorganica Chimica Acta",

issn = "0020-1693",

publisher = "Elsevier B.V.",

number = "2",

}

TY - JOUR

T1 - Solution structures of cobalt-rhodium clusters

T2 - The identification of a new hexanuclear cobalt-rhodium species

AU - Pearsall, Mary-Ann

AU - Horváth, István T.

PY - 1994/12/15

Y1 - 1994/12/15

N2 - The thermolysis of Co2Rh2(CO)12 leads to the quantitative formation of Co3Rh3(CO)16. The solution structures of these clusters have been established by IR and low temperature 13C NMR spectroscopy. Co3Rh3(CO)16 reacts with carbon monoxide at moderate pressure to give the equilibrium mixture of Co2Rh2(CO)12 and CoRh(CO)7. © 1994.

AB - The thermolysis of Co2Rh2(CO)12 leads to the quantitative formation of Co3Rh3(CO)16. The solution structures of these clusters have been established by IR and low temperature 13C NMR spectroscopy. Co3Rh3(CO)16 reacts with carbon monoxide at moderate pressure to give the equilibrium mixture of Co2Rh2(CO)12 and CoRh(CO)7. © 1994.

KW - Cobalt

KW - Mixed-metal carbonyl clusters

KW - Rhodium

UR - http://www.scopus.com/inward/record.url?scp=43949153514&partnerID=8YFLogxK

UR - https://www.scopus.com/record/pubmetrics.uri?eid=2-s2.0-43949153514&origin=recordpage

U2 - 10.1016/0020-1693(94)04210-1

DO - 10.1016/0020-1693(94)04210-1

M3 - RGC 21 - Publication in refereed journal

SN - 0020-1693

VL - 227

SP - 187

EP - 189

JO - Inorganica Chimica Acta

JF - Inorganica Chimica Acta

IS - 2

ER -

Solution structures of cobalt-rhodium clusters: The identification of a new hexanuclear cobalt-rhodium species

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