Solid Nanoporosity Governs Catalytic CO₂ and N₂ Reduction

Global demand for green and clean energy is increasing day by day owing to ongoing developments by the human race that are changing the face of the earth at a rate faster than ever. Exploring alternative sources of energy to replace fossil fuel consumption has become even more vital to control the growing concentration of CO₂, and reduction of CO₂ into CO or other useful hydrocarbons (e.g., C₁ and C_≥2 products), as well as reduction of N₂ into ammonia, can greatly help in this regard. Various materials have been developed for the reduction of CO₂ and N₂. The introduction of pores in these materials by porosity engineering has been demonstrated to be highly effective in increasing the efficiency of the involved redox reactions, over 40% increment for CO₂ reduction to date, by providing an increased number of exposed facets, kinks, edges, and catalytically active sites of catalysts. By shaping the surface porous structure, the selectivity of the redox reaction can also be enhanced. In order to better understand this area benefiting rational design for future solutions, this review systematically summarizes and constructively discusses the porosity engineering in catalytic materials, including various synthesis methods, characterization of porous materials, and the effects of porosity on performance of CO₂ reduction and N₂ reduction.