Slow magnetic relaxation in a mononuclear 8-coordinate Fe(ii) complex

Jing Xiang; Jia-Jia Liu; Xiao-Xiang Chen; Li-Hui Jia; Fei Yu; Bing-Wu Wang; Song Gao; Tai-Chu Lau

doi:10.1039/c6cc09801k

Slow magnetic relaxation in a mononuclear 8-coordinate Fe(ii) complex

Jing Xiang^*, Jia-Jia Liu, Xiao-Xiang Chen, Li-Hui Jia, Fei Yu, Bing-Wu Wang^*, Song Gao^*, Tai-Chu Lau^*

^*Corresponding author for this work

Research output: Journal Publications and Reviews › RGC 21 - Publication in refereed journal › peer-review

42 Citations (Scopus)

Abstract

The synthesis and structure of an 8-coordinate Fe(ii) compound [Fe^II(L₁)₂](ClO₄)₂ (1) with a [FeN₄O₄] core are reported. 1 exhibits uni-axial anisotropy for which a slow magnetic relaxation is observed under 1.4 kOe dc field. It is the first example of an 8-coordinate Fe(ii) complex exhibiting field-induced single-molecule magnet (SMM) behaviour.

Original language	English
Pages (from-to)	1474-1477
Journal	Chemical Communications
Volume	53
Issue number	9
DOIs	https://doi.org/10.1039/c6cc09801k
Publication status	Published - 2017

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title = "Slow magnetic relaxation in a mononuclear 8-coordinate Fe(ii) complex",

abstract = "The synthesis and structure of an 8-coordinate Fe(ii) compound [FeII(L1)2](ClO4)2 (1) with a [FeN4O4] core are reported. 1 exhibits uni-axial anisotropy for which a slow magnetic relaxation is observed under 1.4 kOe dc field. It is the first example of an 8-coordinate Fe(ii) complex exhibiting field-induced single-molecule magnet (SMM) behaviour.",

author = "Jing Xiang and Jia-Jia Liu and Xiao-Xiang Chen and Li-Hui Jia and Fei Yu and Bing-Wu Wang and Song Gao and Tai-Chu Lau",

year = "2017",

doi = "10.1039/c6cc09801k",

language = "English",

volume = "53",

pages = "1474--1477",

journal = "Chemical Communications",

issn = "1359-7345",

publisher = "Royal Society of Chemistry",

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TY - JOUR

T1 - Slow magnetic relaxation in a mononuclear 8-coordinate Fe(ii) complex

AU - Xiang, Jing

AU - Liu, Jia-Jia

AU - Chen, Xiao-Xiang

AU - Jia, Li-Hui

AU - Yu, Fei

AU - Wang, Bing-Wu

AU - Gao, Song

AU - Lau, Tai-Chu

PY - 2017

Y1 - 2017

N2 - The synthesis and structure of an 8-coordinate Fe(ii) compound [FeII(L1)2](ClO4)2 (1) with a [FeN4O4] core are reported. 1 exhibits uni-axial anisotropy for which a slow magnetic relaxation is observed under 1.4 kOe dc field. It is the first example of an 8-coordinate Fe(ii) complex exhibiting field-induced single-molecule magnet (SMM) behaviour.

AB - The synthesis and structure of an 8-coordinate Fe(ii) compound [FeII(L1)2](ClO4)2 (1) with a [FeN4O4] core are reported. 1 exhibits uni-axial anisotropy for which a slow magnetic relaxation is observed under 1.4 kOe dc field. It is the first example of an 8-coordinate Fe(ii) complex exhibiting field-induced single-molecule magnet (SMM) behaviour.

UR - http://www.scopus.com/inward/record.url?scp=85010858490&partnerID=8YFLogxK

UR - https://www.scopus.com/record/pubmetrics.uri?eid=2-s2.0-85010858490&origin=recordpage

U2 - 10.1039/c6cc09801k

DO - 10.1039/c6cc09801k

M3 - RGC 21 - Publication in refereed journal

SN - 1359-7345

VL - 53

SP - 1474

EP - 1477

JO - Chemical Communications

JF - Chemical Communications

IS - 9

ER -

Slow magnetic relaxation in a mononuclear 8-coordinate Fe(ii) complex

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