Single-photon vacuum-ultraviolet laser-pulsed-field ionization-photoelectron studies of trans- and cis-1-bromopropenes
Research output: Journal Publications and Reviews › RGC 21 - Publication in refereed journal › peer-review
Author(s)
Detail(s)
Original language | English |
---|---|
Pages (from-to) | 9561-9570 |
Journal / Publication | Journal of Chemical Physics |
Volume | 120 |
Issue number | 20 |
Publication status | Published - 22 May 2004 |
Externally published | Yes |
Link(s)
Abstract
A study of the vacuum ultraviolet pulsed field ionization-photoelectron (VUV-PFI-PE) spectra of trans and cis-1 bromopropenes in the energy region of 74 720-76 840 cm-1 was presented. The resolved vibrational bands in the PFI-PE spectra were assigned using theoretical vibrational frequencies and FCF simulations. It was found that both PFI-PE vibrational bands for trans-CH3-CHBr+ and CIS-ch3=chbR+ exhibited partially resolved rotational contours. The good fits of the origin PFI-PE vibrational bands for the compounds were obtained using a semiempirical simulation scheme together with theoretical rotational constants.
Citation Format(s)
Single-photon vacuum-ultraviolet laser-pulsed-field ionization-photoelectron studies of trans- and cis-1-bromopropenes. / Woo, H. K.; Wang, P.; Lau, K.-C. et al.
In: Journal of Chemical Physics, Vol. 120, No. 20, 22.05.2004, p. 9561-9570.
In: Journal of Chemical Physics, Vol. 120, No. 20, 22.05.2004, p. 9561-9570.
Research output: Journal Publications and Reviews › RGC 21 - Publication in refereed journal › peer-review