Single microcrystals of organoplatinum(II) complexes with high charge-carrier mobility

Chi-Ming Che; Cheuk-Fai Chow; Mai-Yan Yuen; V. A L Roy; Wei Lu; Yong Chen; Stephen Sin-Yin Chui; Nianyong Zhu

doi:10.1039/c0sc00479k

Single microcrystals of organoplatinum(II) complexes with high charge-carrier mobility

Chi-Ming Che, Cheuk-Fai Chow, Mai-Yan Yuen, V. A L Roy, Wei Lu, Yong Chen, Stephen Sin-Yin Chui, Nianyong Zhu

Research output: Journal Publications and Reviews › RGC 21 - Publication in refereed journal › peer-review

52 Citations (Scopus)

Abstract

Hydrogen-bonding pyrazolyl and imidazolyl motifs are incorporated into organoplatinum(II) complexes and found to be harmonized with extended π - π and Pt^II ...Pt^II interactions to align the planar cations into a quasi-1-D columnar structure or a quasi-2D framework. A field-effect electron mobility up to 20 cm²V^-1s^-1 has been recorded with a single-microcrystal transistor. In addition, crystalline samples of one of the organoplatinum(II) complexes show intriguing thermoluminescent and vapoluminescent properties. © The Royal Society of Chemistry 2011.

Original language	English
Pages (from-to)	216-220
Journal	Chemical Science
Volume	2
Issue number	2
DOIs	https://doi.org/10.1039/c0sc00479k
Publication status	Published - 2011

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title = "Single microcrystals of organoplatinum(II) complexes with high charge-carrier mobility",

abstract = "Hydrogen-bonding pyrazolyl and imidazolyl motifs are incorporated into organoplatinum(II) complexes and found to be harmonized with extended π - π and PtII ...PtII interactions to align the planar cations into a quasi-1-D columnar structure or a quasi-2D framework. A field-effect electron mobility up to 20 cm2V-1s-1 has been recorded with a single-microcrystal transistor. In addition, crystalline samples of one of the organoplatinum(II) complexes show intriguing thermoluminescent and vapoluminescent properties. {\textcopyright} The Royal Society of Chemistry 2011.",

author = "Chi-Ming Che and Cheuk-Fai Chow and Mai-Yan Yuen and Roy, {V. A L} and Wei Lu and Yong Chen and Chui, {Stephen Sin-Yin} and Nianyong Zhu",

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doi = "10.1039/c0sc00479k",

language = "English",

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T1 - Single microcrystals of organoplatinum(II) complexes with high charge-carrier mobility

AU - Che, Chi-Ming

AU - Chow, Cheuk-Fai

AU - Yuen, Mai-Yan

AU - Roy, V. A L

AU - Lu, Wei

AU - Chen, Yong

AU - Chui, Stephen Sin-Yin

AU - Zhu, Nianyong

PY - 2011

Y1 - 2011

N2 - Hydrogen-bonding pyrazolyl and imidazolyl motifs are incorporated into organoplatinum(II) complexes and found to be harmonized with extended π - π and PtII ...PtII interactions to align the planar cations into a quasi-1-D columnar structure or a quasi-2D framework. A field-effect electron mobility up to 20 cm2V-1s-1 has been recorded with a single-microcrystal transistor. In addition, crystalline samples of one of the organoplatinum(II) complexes show intriguing thermoluminescent and vapoluminescent properties. © The Royal Society of Chemistry 2011.

AB - Hydrogen-bonding pyrazolyl and imidazolyl motifs are incorporated into organoplatinum(II) complexes and found to be harmonized with extended π - π and PtII ...PtII interactions to align the planar cations into a quasi-1-D columnar structure or a quasi-2D framework. A field-effect electron mobility up to 20 cm2V-1s-1 has been recorded with a single-microcrystal transistor. In addition, crystalline samples of one of the organoplatinum(II) complexes show intriguing thermoluminescent and vapoluminescent properties. © The Royal Society of Chemistry 2011.

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U2 - 10.1039/c0sc00479k

DO - 10.1039/c0sc00479k

M3 - RGC 21 - Publication in refereed journal

SN - 2041-6520

VL - 2

SP - 216

EP - 220

JO - Chemical Science

JF - Chemical Science

IS - 2

ER -

Single microcrystals of organoplatinum(II) complexes with high charge-carrier mobility

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