Simultaneous removal of NO_X and SO₂ from flue gas in an integrated FGD-CABR system by sulfur cycling-mediated Fe(II)EDTA regeneration

Chemical absorption-biological reduction (CABR) process is an attractive method for NO_X removal and Fe(II)EDTA regeneration is important to sustain high NO_X removal. In this study a sustainable and eco-friendly sulfur cycling-mediated Fe(II)EDTA regeneration method was incorporated in the integrated biological flue gas desulfurization (FGD)-CABR system. Here, we investigated the NO_X and SO₂ removal efficiency of the system under three different flue gas flows (100 mL/min, 500 mL/min, and 1000 mL/min) and evaluated the feasibility of chemical Fe(III)EDTA reduction by sulfide in series of batch tests. Our results showed that complete SO₂ removal was achieved at all the tested scenarios with sulfide, thiosulfate and S⁰ accumulation in the solution. Meanwhile, the total removal efficiency of NO_X achieved ∼100% in the system, of which 3.2%–23.3% was removed in spray scrubber and 76.7%–96.5% in EGSB reactor along with no N₂O emission. The optimal pH and S²⁻/Fe(III)EDTA for Fe(II)EDTA regeneration and S⁰ recovery was 8.0 and 1:2. The microbial community analysis results showed that the cooperation of heterotrophic denitrifier (Saprospiraceae_uncultured and Dechloromonas) and iron-reducing bacteria (Klebsiella and Petrimonas) in EGSB reactor and sulfide-oxidizing, nitrate-reducing bacteria (Azoarcus and Pseudarcobacter) in spray scrubber contributed to the efficient removal of NO_X in flue gas.