Simultaneous online measurement of sulfide and nitrate in sewers for nitrate dosage optimisation

Oriol Gutierrez, Luke Sutherland-Stacey, Zhiguo Yuan

Research output: Journal Publications and ReviewsRGC 21 - Publication in refereed journalpeer-review

23 Citations (Scopus)

Abstract

A new method for the simultaneous online measurement of sulfide and nitrate in wastewater is developed. A UV-VIS spectrometer was used. The sensor was calibrated by means of simultaneous online and offline measurements of sulfide and nitrate in batch tests carried out on a laboratory-scale sewer system. The developed calibration algorithm was successfully validated for both sulfide and nitrate measurement, with confidence limits of 2.7mg S/L for total dissolved sulfide, and 7.5mg N/L for nitrate. The online measurement of sulfide and nitrate enabled detailed evaluation of seven nitrate dosing strategies in the laboratory-scale sewer system, providing strong support to process optimisation. The dosage optimisation revealed that nitrate should be added at a location close to the point of sulfide control rather than at the beginning of a rising main, at a rate proportional to the expected hydraulic retention time (HRT) of the wastewater in the sewer section between the point of nitrate addition and the point where sulfide control is desired. © IWA Publishing 2010.
Original languageEnglish
Pages (from-to)651-658
JournalWater Science and Technology
Volume61
Issue number3
DOIs
Publication statusPublished - 2010
Externally publishedYes

Bibliographical note

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Research Keywords

  • Dosage optimisation
  • Nitrate
  • Sewer
  • Sulfide
  • UV-VIS spectrometry

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