Simultaneous fire safety enhancement and mechanical reinforcement of poly(lactic acid) biocomposites with hexaphenyl (nitrilotris(ethane-2,1-diyl))tris(phosphoramidate)

Poly(lactic acid) (PLA) is an important bioplastic polymer with wide engineering applications, but has relatively low tensile strength and high susceptibility to flames. This manuscript reports the synthesis of a new cyclo-phosphorus-nitrogen flame retardant (FR) - hexaphenyl (nitrilotris(ethane-2,1-diyl))tris(phosphoramidate) (HNETP) for concurrent FR and tensile strength enhancement. ¹H, ¹³C Nuclear Magnetic Resonance and Fourier Transform Infra-red spectra showed that HNETP was successfully synthesized. The FR properties of PLA/HNETP composites were investigated, and the peak heat release rate (PHRR) reduced by ˜ 51.3%, total heat released (THR) ˜ 43.1%, and carbon monoxide (CO) production by ˜ 46.5% with 3 wt% HNETP loading. The fire performance index increased by ˜ 65.8%, while the fire growth index decreased by ˜ 56.7%. The tensile strength and the Young's Modulus improved to ˜ 67.4 and ˜ 87.8% respectively. A significant increase in limiting oxygen index (LOI) (32.5%) was attained with a V-0 rating in the vertical burning test. TG-IR study showed considerable reduction in pyrolysis gaseous products by the PLA/HNETP composites compared to PLA. Insignificant changes were observed in the glass transition and the melting temperature of PLA and PLA/HNETP biocomposites.