Si-based solid blue emitters from 3C-SiC nanocrystals

A procedure for preparing 3C-SiC/SiO₂ composite nanocrystals embedded in Si matrix that emit blue light is reported. Through electrochemical etching of polycrystalline 3C-SiC wafers followed by ultrasonic treatment in water bath, we fabricated luminescent colloidal 3C-SiC nanocrystals. Porous Si samples that have been naturally oxidized in air for 12 h were immersed in agitated aqueous suspension of 3C-SiC nanocrystals for 10 min and then dried in air, followed by annealing in argon atmosphere to form core-shell structured 3C-SiC/SiO₂ nanocrystals embedded in Si matrix. Our result shows that the luminescence of 3C-SiC/SiO₂ composite nanocrystals is very stable over time or under high temperature. As robust and stable Si-based solid blue-emitters, they have important implications for engineering photonic components in optoelectronics and photonics.