Self-reversal effect elimination in laser-induced breakdown spectroscopy by employing single-probe microwave radiation
Research output: Journal Publications and Reviews › RGC 21 - Publication in refereed journal › peer-review
Author(s)
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Detail(s)
Original language | English |
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Pages (from-to) | 1713–1719 |
Journal / Publication | Journal of Analytical Atomic Spectrometry |
Volume | 38 |
Issue number | 8 |
Online published | 18 Jul 2023 |
Publication status | Published - 1 Aug 2023 |
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Abstract
The self-absorption effect in laser-induced breakdown spectroscopy (LIBS) has always been a bottleneck that causes spectral distortion even self-reversal, and poor quantitative accuracy, limiting the engineering application of LIBS. Microwave-assisted LIBS (MA-LIBS) has proven to be feasible to weaken the self-absorption effect, but the stability of microwave excitation and the microwave radiator need to be improved. In this study, a new single-probe microwave radiator was proposed to achieve superior injection of microwave power for the elimination of the self-reversal effect. The electromagnetic simulations of the single-probe radiator were first conducted for efficient microwave coupling. To evaluate the performance of the single-probe radiator, the effect of microwave parameters on self-reversal elimination of typical self-absorption elements sodium (Na) and potassium (K) in potassium feldspar samples was investigated and optimized. With the increase in microwave power, self-reversal was eliminated. Also, spectral evolution measurements have been performed and the results indicated significant self-reversal elimination and prolonged plasma lifetime in MA-LIBS. The results indicated that MA-LIBS with single-probe microwave excitation showed excellent potential in eliminating the self-reversal phenomenon and provided technical support for the application of LIBS. © The Royal Society of Chemistry 2023.
Research Area(s)
- ABSORPTION REDUCTION, PLASMA
Citation Format(s)
Self-reversal effect elimination in laser-induced breakdown spectroscopy by employing single-probe microwave radiation. / Fan, Yue; Gu, Yang; Hu, Zhenlin et al.
In: Journal of Analytical Atomic Spectrometry, Vol. 38, No. 8, 01.08.2023, p. 1713–1719.
In: Journal of Analytical Atomic Spectrometry, Vol. 38, No. 8, 01.08.2023, p. 1713–1719.
Research output: Journal Publications and Reviews › RGC 21 - Publication in refereed journal › peer-review