Self-isomerization of nearly planar superatoms formed by actinide embedded gold clusters

Research output: Journal Publications and Reviews › RGC 21 - Publication in refereed journal › peer-review

View graph of relations

Author(s)

  • Zheng Liu
  • Yang Gao
  • Famin Yu
  • Zhonghua Liu
  • Jiarui Li
  • Yan Xue
  • Zhigang Wang

Related Research Unit(s)

Detail(s)

Original languageEnglish
Pages (from-to)1612-1615
Journal / PublicationPhysical Chemistry Chemical Physics
Volume25
Issue number3
Online published15 Dec 2022
Publication statusPublished - 21 Jan 2023

Link(s)

DOI

DOI
Check@CityULib
Link to Scopus https://www.scopus.com/record/display.uri?eid=2-s2.0-85146324012&origin=recordpage
Permanent Link https://scholars.cityu.edu.hk/en/publications/publication(f9527264-c687-4fcb-b1e4-c596f76338ac).html

Abstract

First-principles calculations show a self-isomerization process of the nearly planar superatom, in which the maximum energy difference between different extreme points is below 0.1 eV and a crossing between singlet and triplet states is also involved. Further UV-Vis spectra reveal a correlation between the spectra and structures caused by self-isomerization.

Research Area(s)

  • ORBITALS

Fingerprint

Publication fingerprints text

100
Isomerization Keyphrases
100
Gold Clusters Keyphrases
100
Actinides Keyphrases
100
Superatoms Keyphrases
100
Actinoid Atom Chemistry
100
isomerization INIS
100
gold INIS
100
actinides INIS
66
Spectra Chemistry
50
First-principles Ca... Keyphrases
Full Fingerprint ›

Citation Format(s)

[ RIS ] [ BibTeX ]
Self-isomerization of nearly planar superatoms formed by actinide embedded gold clusters. / Liu, Zheng; Gao, Yang; Yu, Famin et al.
In: Physical Chemistry Chemical Physics, Vol. 25, No. 3, 21.01.2023, p. 1612-1615.

Research output: Journal Publications and Reviews › RGC 21 - Publication in refereed journal › peer-review