Self-sustained and Insulated Radiative/Evaporative Cooler for Daytime Subambient Passive Cooling

Passive cooling technologies are one of the promising solutions to the global energy crisis due to no consumption of fossil fuels during operation. However, the existing radiative and evaporative coolers still have problems achieving daytime subambient cooling while maintaining evaporation over the long term. Here, we propose a self-sustained and insulated radiative/evaporative cooler (SIREC), which consists of a porous polyethylene film (P-PE) at the top, an air layer in the middle, and poly(vinyl alcohol) hydrogel with lithium bromide (PLH) at the bottom. In particular, the P-PE shows high solar reflectance (R̅_solar = 0.91) and long-wave infrared transmittance (τ̅_LWIR = 0.92), which reflects sunlight while enhancing the direct radiative heat transfer between outer space and PLH (ϵ̅_LWIR = 0.96) for sky radiative cooling. In addition, the desirable vapor permeability (579 s m^-1) of the P-PE also results in good compatibility with PLH for evaporative cooling (EC). Moreover, the PLH’s ability to harvest atmospheric water at night provides self-sustainment for daytime EC. The air layer between P-PE and PLH further enhances the subambient cooling performance of the SIREC. These findings indicate promising prospects for the integration of passive cooling technologies. © 2024 American Chemical Society