Self-assembly, crystal structure, and magnetic properties of a phenoxo- bridged tetranuclear CuII complex of the [2 x 2] grid type

Javier Rojo; Jean-Marie Lehn; Gerhard Baum; Dieter Fenske; Oliver Waldmann; Paul Müller

doi:10.1002/(SICI)1099-0682(199903)1999:3<517::AID-EJIC517>3.0.CO;2-D

Self-assembly, crystal structure, and magnetic properties of a phenoxo- bridged tetranuclear Cu^II complex of the [2 x 2] grid type

Javier Rojo
, Jean-Marie Lehn^*
, Gerhard Baum
, Dieter Fenske
, Oliver Waldmann
, Paul Müller

^*Corresponding author for this work

Research output: Journal Publications and Reviews › RGC 21 - Publication in refereed journal › peer-review

62 Citations (Scopus)

Abstract

The ditopic ligand 3 has been synthesized. In its deprotonated form, it reacts with copper(II) ions to form a tetranuclear complex 1 of the [2 x 2] Cu^II₄ grid type, the structure of which has been confirmed by X-ray crystallography. Magnetic studies of complex 1 indicate a very weak antiferromagnetic coupling between the phenoxo-bridged Cuu^II ions. © 1999 WILEY-VCH Verlag GmbH, Weinheim, Fed. Rep. of Germany

Original language	English
Pages (from-to)	517-522
Journal	European Journal of Inorganic Chemistry
Issue number	3
DOIs	https://doi.org/10.1002/(SICI)1099-0682(199903)1999:3<517::AID-EJIC517>3.0.CO;2-D
Publication status	Published - Mar 1999
Externally published	Yes

Research Keywords

[2 x 2] grid-type complex
Crystal structure
Magnetic properties
Self-assembly
Tetranuclear Cu(II) complex

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10.1002/(SICI)1099-0682(199903)1999:3<517::AID-EJIC517>3.0.CO;2-D

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Cite this

@article{5c70b2b768f34a399b9255469e1f3130,

title = "Self-assembly, crystal structure, and magnetic properties of a phenoxo- bridged tetranuclear CuII complex of the [2 x 2] grid type",

abstract = "The ditopic ligand 3 has been synthesized. In its deprotonated form, it reacts with copper(II) ions to form a tetranuclear complex 1 of the [2 x 2] CuII4 grid type, the structure of which has been confirmed by X-ray crystallography. Magnetic studies of complex 1 indicate a very weak antiferromagnetic coupling between the phenoxo-bridged CuuII ions. {\textcopyright} 1999 WILEY-VCH Verlag GmbH, Weinheim, Fed. Rep. of Germany",

keywords = "[2 x 2] grid-type complex, Crystal structure, Magnetic properties, Self-assembly, Tetranuclear Cu(II) complex",

author = "Javier Rojo and Jean-Marie Lehn and Gerhard Baum and Dieter Fenske and Oliver Waldmann and Paul M{\"u}ller",

year = "1999",

month = mar,

doi = "10.1002/(SICI)1099-0682(199903)1999:3<517::AID-EJIC517>3.0.CO;2-D",

language = "English",

pages = "517--522",

journal = "European Journal of Inorganic Chemistry",

issn = "1434-1948",

publisher = "Wiley-VCH Verlag GmbH",

number = "3",

}

Self-assembly, crystal structure, and magnetic properties of a phenoxo- bridged tetranuclear Cu^II complex of the [2 x 2] grid type. / Rojo, Javier; Lehn, Jean-Marie; Baum, Gerhard et al.
In: European Journal of Inorganic Chemistry, No. 3, 03.1999, p. 517-522.

Research output: Journal Publications and Reviews › RGC 21 - Publication in refereed journal › peer-review

TY - JOUR

T1 - Self-assembly, crystal structure, and magnetic properties of a phenoxo- bridged tetranuclear CuII complex of the [2 x 2] grid type

AU - Rojo, Javier

AU - Lehn, Jean-Marie

AU - Baum, Gerhard

AU - Fenske, Dieter

AU - Waldmann, Oliver

AU - Müller, Paul

PY - 1999/3

Y1 - 1999/3

N2 - The ditopic ligand 3 has been synthesized. In its deprotonated form, it reacts with copper(II) ions to form a tetranuclear complex 1 of the [2 x 2] CuII4 grid type, the structure of which has been confirmed by X-ray crystallography. Magnetic studies of complex 1 indicate a very weak antiferromagnetic coupling between the phenoxo-bridged CuuII ions. © 1999 WILEY-VCH Verlag GmbH, Weinheim, Fed. Rep. of Germany

AB - The ditopic ligand 3 has been synthesized. In its deprotonated form, it reacts with copper(II) ions to form a tetranuclear complex 1 of the [2 x 2] CuII4 grid type, the structure of which has been confirmed by X-ray crystallography. Magnetic studies of complex 1 indicate a very weak antiferromagnetic coupling between the phenoxo-bridged CuuII ions. © 1999 WILEY-VCH Verlag GmbH, Weinheim, Fed. Rep. of Germany

KW - [2 x 2] grid-type complex

KW - Crystal structure

KW - Magnetic properties

KW - Self-assembly

KW - Tetranuclear Cu(II) complex

UR - https://www.scopus.com/pages/publications/0032818836

UR - https://www.scopus.com/record/pubmetrics.uri?eid=2-s2.0-0032818836&origin=recordpage

U2 - 10.1002/(SICI)1099-0682(199903)1999:3<517::AID-EJIC517>3.0.CO;2-D

DO - 10.1002/(SICI)1099-0682(199903)1999:3<517::AID-EJIC517>3.0.CO;2-D

M3 - RGC 21 - Publication in refereed journal

SN - 1434-1948

SP - 517

EP - 522

JO - European Journal of Inorganic Chemistry

JF - European Journal of Inorganic Chemistry

IS - 3

ER -