Ruthenium catalysed oxidation of alkanes with alkylhydroperoxides

Research output: Journal Publications and Reviews (RGC: 21, 22, 62) › 22_Publication in policy or professional journal

Overview

89 Scopus Citations

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Author(s)

Tai-Chu Lau
Chi-Ming Che
Wai-On Lee
Chung-Kwong Poon

Detail(s)

Original language	English
Pages (from-to)	1406-1407
Journal / Publication	Journal of the Chemical Society, Chemical Communications
Issue number	21
Publication status	Published - 1988
Externally published	Yes

Link(s)

DOI	DOI https://doi.org/10.1039/C39880001406 Final Published version
	Check@CityULib
Link to Scopus	https://www.scopus.com/record/display.uri?eid=2-s2.0-37049076667&origin=recordpage
Permanent Link	https://scholars.cityu.edu.hk/en/publications/publication(c79b356d-d5c1-4232-9681-771724214e42).html

Abstract

The cis-[Ru^II(L)₂(OH₂)₂] ²⁺ complexes (L = substituted 2,2′-bipyridines or 1,10-phenanthrolines) catalyse oxidation of saturated hydrocarbons to alcohols and ketones by t-butylhydroperoxide; the low values of kinetic isotope effect (k_H/k_D = 3.5 for cyclohexane) and tertiary of secondary C-H bond relative reactivities (k_tert/k_sec ca. 6.5 for adamantane) are in a range expected for hydrogen atom abstraction by radical species.

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Publication fingerprints text

Adamantane Medicine & Life Sciences

tert-Butylhydropero... Medicine & Life Sciences

2,2'-Dipyridyl Medicine & Life Sciences

Alkanes Medicine & Life Sciences

Phenanthrolines Medicine & Life Sciences

Ruthenium Medicine & Life Sciences

Hydrocarbons Medicine & Life Sciences

Ketones Medicine & Life Sciences

Isotopes Medicine & Life Sciences

Hydrogen Medicine & Life Sciences

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Citation Format(s)

[ RIS ] [ BibTeX ]

Ruthenium catalysed oxidation of alkanes with alkylhydroperoxides. / Lau, Tai-Chu; Che, Chi-Ming; Lee, Wai-On et al.

In: Journal of the Chemical Society, Chemical Communications, No. 21, 1988, p. 1406-1407.

Research output: Journal Publications and Reviews (RGC: 21, 22, 62) › 22_Publication in policy or professional journal

Lau, T-C, Che, C-M, Lee, W-O & Poon, C-K 1988, 'Ruthenium catalysed oxidation of alkanes with alkylhydroperoxides', Journal of the Chemical Society, Chemical Communications, no. 21, pp. 1406-1407. https://doi.org/10.1039/C39880001406

Lau, T-C., Che, C-M., Lee, W-O., & Poon, C-K. (1988). Ruthenium catalysed oxidation of alkanes with alkylhydroperoxides. Journal of the Chemical Society, Chemical Communications, (21), 1406-1407. https://doi.org/10.1039/C39880001406

Lau T-C, Che C-M, Lee W-O, Poon C-K. Ruthenium catalysed oxidation of alkanes with alkylhydroperoxides. Journal of the Chemical Society, Chemical Communications. 1988;(21):1406-1407. doi: 10.1039/C39880001406

Lau, Tai-Chu ; Che, Chi-Ming ; Lee, Wai-On et al. / Ruthenium catalysed oxidation of alkanes with alkylhydroperoxides. In: Journal of the Chemical Society, Chemical Communications. 1988 ; No. 21. pp. 1406-1407.