Room-temperature acetylene hydration by a Hg(II)-laced metal-organic framework

Ka-Kit Yee; Yan-Lung Wong; Meiqin Zha; Ramesh Y. Adhikari; Mark T. Tuominen; Jun He; Zhengtao Xu

doi:10.1039/c5cc03943f

Room-temperature acetylene hydration by a Hg(II)-laced metal-organic framework

Ka-Kit Yee, Yan-Lung Wong, Meiqin Zha, Ramesh Y. Adhikari, Mark T. Tuominen, Jun He, Zhengtao Xu^*

^*Corresponding author for this work

Research output: Journal Publications and Reviews › RGC 21 - Publication in refereed journal › peer-review

47 Citations (Scopus)

Abstract

Thiol (-SH) groups within a Zr(iv)-based metal-organic framework (MOF) anchor Hg(ii) atoms; oxidation by H₂O₂ then leads to acidic sulfonate functions for catalyzing acetylene hydration at room temperature.

Original language	English
Pages (from-to)	10941-10944
Journal	Chemical Communications
Volume	51
Issue number	54
Online published	27 May 2015
DOIs	https://doi.org/10.1039/c5cc03943f
Publication status	Published - 11 Jul 2015

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title = "Room-temperature acetylene hydration by a Hg(II)-laced metal-organic framework",

abstract = "Thiol (-SH) groups within a Zr(iv)-based metal-organic framework (MOF) anchor Hg(ii) atoms; oxidation by H2O2 then leads to acidic sulfonate functions for catalyzing acetylene hydration at room temperature.",

author = "Ka-Kit Yee and Yan-Lung Wong and Meiqin Zha and Adhikari, {Ramesh Y.} and Tuominen, {Mark T.} and Jun He and Zhengtao Xu",

year = "2015",

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day = "11",

doi = "10.1039/c5cc03943f",

language = "English",

volume = "51",

pages = "10941--10944",

journal = "Chemical Communications",

issn = "0009-241X",

publisher = "Royal Society of Chemistry",

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TY - JOUR

T1 - Room-temperature acetylene hydration by a Hg(II)-laced metal-organic framework

AU - Yee, Ka-Kit

AU - Wong, Yan-Lung

AU - Zha, Meiqin

AU - Adhikari, Ramesh Y.

AU - Tuominen, Mark T.

AU - He, Jun

AU - Xu, Zhengtao

PY - 2015/7/11

Y1 - 2015/7/11

N2 - Thiol (-SH) groups within a Zr(iv)-based metal-organic framework (MOF) anchor Hg(ii) atoms; oxidation by H2O2 then leads to acidic sulfonate functions for catalyzing acetylene hydration at room temperature.

AB - Thiol (-SH) groups within a Zr(iv)-based metal-organic framework (MOF) anchor Hg(ii) atoms; oxidation by H2O2 then leads to acidic sulfonate functions for catalyzing acetylene hydration at room temperature.

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U2 - 10.1039/c5cc03943f

DO - 10.1039/c5cc03943f

M3 - RGC 21 - Publication in refereed journal

SN - 0009-241X

VL - 51

SP - 10941

EP - 10944

JO - Chemical Communications

JF - Chemical Communications

IS - 54

ER -

Room-temperature acetylene hydration by a Hg(II)-laced metal-organic framework

Abstract

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