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Role of fluorine in plasma nitridated ZrO2 thin films under irradiation

  • A. P. Huang
  • , Z. S. Xiao
  • , X. Y. Liu
  • , L. Wang
  • , Paul K. Chu

    Research output: Journal Publications and ReviewsRGC 21 - Publication in refereed journalpeer-review

    Abstract

    The role of fluorine in plasma-nitridated ZrO2 thin films under electron irradiation is investigated in situ by real-time high-resolution transmission electron microscopy. Fluorine and nitrogen codoping can suppress the microstructure evolution during electron beam bombardment and the corresponding origin is probed and verified. The results obtained by irradiation with an ultraviolet laser show that plasma fluorination can effectively remove the dissociative N or O particles in the ZrO2 thin films which can escape from the interstitial sites under electron irradiation. The mechanism of the irradiation stability of the F and N codoped ZrO2 thin film is also discussed. © 2008 American Institute of Physics.
    Original languageEnglish
    Article number122907
    JournalApplied Physics Letters
    Volume93
    Issue number12
    DOIs
    Publication statusPublished - 2008

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