Rhoda-Electrocatalyzed Bimetallic C−H Oxygenation by Weak O-Coordination

Xuefeng Tan; Leonardo Massignan; Xiaoyan Hou; Johanna Frey; João C. A. Oliveira; Masoom Nasiha Hussain; Lutz Ackermann

doi:10.1002/anie.202017359

Author(s)

Leonardo Massignan
Xiaoyan Hou
Johanna Frey
João C. A. Oliveira
Masoom Nasiha Hussain
Lutz Ackermann

Detail(s)

Original language	English
Pages (from-to)	13264-13270
Journal / Publication	Angewandte Chemie - International Edition
Volume	60
Issue number	24
Online published	2 Mar 2021
Publication status	Published - 7 Jun 2021
Externally published	Yes

Link(s)

DOI	DOI https://doi.org/10.1002/anie.202017359 Final Published version
	Check@CityULib
Link to Scopus	https://www.scopus.com/record/display.uri?eid=2-s2.0-85105046801&origin=recordpage
Permanent Link	https://scholars.cityu.edu.hk/en/publications/publication(16a07d37-4734-440a-97b2-5f7aade3bf7b).html

Abstract

Rhodium-electrocatalyzed arene C−H oxygenation by weakly O-coordinating amides and ketones have been established by bimetallic electrocatalysis. Likewise, diverse dihydrooxazinones were selectively accessed by the judicious choice of current, enabling twofold C−H functionalization. Detailed mechanistic studies by experiment, mass spectroscopy and cyclovoltammetric analysis provided support for an unprecedented electrooxidation-induced C−H activation by a bimetallic rhodium catalysis manifold. © 2021 The Authors. Angewandte Chemie International Edition published by Wiley-VCH GmbH

Research Area(s)

cascade, C−H activation, electrochemistry, oxygenation, rhodium

Citation Format(s)

[ RIS ] [ BibTeX ]

Rhoda-Electrocatalyzed Bimetallic C−H Oxygenation by Weak O-Coordination. / Tan, Xuefeng; Massignan, Leonardo; Hou, Xiaoyan et al.
In: Angewandte Chemie - International Edition, Vol. 60, No. 24, 07.06.2021, p. 13264-13270.

Research output: Journal Publications and Reviews › RGC 21 - Publication in refereed journal › peer-review

Tan, X, Massignan, L, Hou, X, Frey, J, Oliveira, JCA, Hussain, MN & Ackermann, L 2021, 'Rhoda-Electrocatalyzed Bimetallic C−H Oxygenation by Weak O-Coordination', Angewandte Chemie - International Edition, vol. 60, no. 24, pp. 13264-13270. https://doi.org/10.1002/anie.202017359

Tan, X., Massignan, L., Hou, X., Frey, J., Oliveira, J. C. A., Hussain, M. N., & Ackermann, L. (2021). Rhoda-Electrocatalyzed Bimetallic C−H Oxygenation by Weak O-Coordination. Angewandte Chemie - International Edition, 60(24), 13264-13270. https://doi.org/10.1002/anie.202017359

Tan X, Massignan L, Hou X, Frey J, Oliveira JCA, Hussain MN et al. Rhoda-Electrocatalyzed Bimetallic C−H Oxygenation by Weak O-Coordination. Angewandte Chemie - International Edition. 2021 Jun 7;60(24):13264-13270. Epub 2021 Mar 2. doi: 10.1002/anie.202017359

Tan, Xuefeng ; Massignan, Leonardo ; Hou, Xiaoyan et al. / Rhoda-Electrocatalyzed Bimetallic C−H Oxygenation by Weak O-Coordination. In: Angewandte Chemie - International Edition. 2021 ; Vol. 60, No. 24. pp. 13264-13270.