Rhoda-Electrocatalyzed Bimetallic C−H Oxygenation by Weak O-Coordination

Research output: Journal Publications and ReviewsRGC 21 - Publication in refereed journalpeer-review

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Author(s)

  • Leonardo Massignan
  • Xiaoyan Hou
  • Johanna Frey
  • João C. A. Oliveira
  • Masoom Nasiha Hussain
  • Lutz Ackermann

Detail(s)

Original languageEnglish
Pages (from-to)13264-13270
Journal / PublicationAngewandte Chemie - International Edition
Volume60
Issue number24
Online published2 Mar 2021
Publication statusPublished - 7 Jun 2021
Externally publishedYes

Abstract

Rhodium-electrocatalyzed arene C−H oxygenation by weakly O-coordinating amides and ketones have been established by bimetallic electrocatalysis. Likewise, diverse dihydrooxazinones were selectively accessed by the judicious choice of current, enabling twofold C−H functionalization. Detailed mechanistic studies by experiment, mass spectroscopy and cyclovoltammetric analysis provided support for an unprecedented electrooxidation-induced C−H activation by a bimetallic rhodium catalysis manifold. © 2021 The Authors. Angewandte Chemie International Edition published by Wiley-VCH GmbH

Research Area(s)

  • cascade, C−H activation, electrochemistry, oxygenation, rhodium

Citation Format(s)

Rhoda-Electrocatalyzed Bimetallic C−H Oxygenation by Weak O-Coordination. / Tan, Xuefeng; Massignan, Leonardo; Hou, Xiaoyan et al.
In: Angewandte Chemie - International Edition, Vol. 60, No. 24, 07.06.2021, p. 13264-13270.

Research output: Journal Publications and ReviewsRGC 21 - Publication in refereed journalpeer-review