TY - JOUR
T1 - Rhoda-Electrocatalyzed Bimetallic C−H Oxygenation by Weak O-Coordination
AU - Tan, Xuefeng
AU - Massignan, Leonardo
AU - Hou, Xiaoyan
AU - Frey, Johanna
AU - Oliveira, João C. A.
AU - Hussain, Masoom Nasiha
AU - Ackermann, Lutz
PY - 2021/6/7
Y1 - 2021/6/7
N2 - Rhodium-electrocatalyzed arene C−H oxygenation by weakly O-coordinating amides and ketones have been established by bimetallic electrocatalysis. Likewise, diverse dihydrooxazinones were selectively accessed by the judicious choice of current, enabling twofold C−H functionalization. Detailed mechanistic studies by experiment, mass spectroscopy and cyclovoltammetric analysis provided support for an unprecedented electrooxidation-induced C−H activation by a bimetallic rhodium catalysis manifold. © 2021 The Authors. Angewandte Chemie International Edition published by Wiley-VCH GmbH
AB - Rhodium-electrocatalyzed arene C−H oxygenation by weakly O-coordinating amides and ketones have been established by bimetallic electrocatalysis. Likewise, diverse dihydrooxazinones were selectively accessed by the judicious choice of current, enabling twofold C−H functionalization. Detailed mechanistic studies by experiment, mass spectroscopy and cyclovoltammetric analysis provided support for an unprecedented electrooxidation-induced C−H activation by a bimetallic rhodium catalysis manifold. © 2021 The Authors. Angewandte Chemie International Edition published by Wiley-VCH GmbH
KW - cascade
KW - C−H activation
KW - electrochemistry
KW - oxygenation
KW - rhodium
UR - http://www.scopus.com/inward/record.url?scp=85105046801&partnerID=8YFLogxK
UR - https://www.scopus.com/record/pubmetrics.uri?eid=2-s2.0-85105046801&origin=recordpage
U2 - 10.1002/anie.202017359
DO - 10.1002/anie.202017359
M3 - RGC 21 - Publication in refereed journal
C2 - 33651910
SN - 1433-7851
VL - 60
SP - 13264
EP - 13270
JO - Angewandte Chemie - International Edition
JF - Angewandte Chemie - International Edition
IS - 24
ER -