Reversible photochromic and photoluminescence in iodide perovskites

Research output: Journal Publications and Reviews (RGC: 21, 22, 62)21_Publication in refereed journalpeer-review

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Author(s)

  • Wayesh Qarony
  • Mohammad Ismail Hossain
  • Longhui Zeng
  • Sainan Ma
  • Alberto Salleo
  • Dietmar Knipp
  • Cho Tung Yip
  • Yuen Hong Tsang

Related Research Unit(s)

Detail(s)

Original languageEnglish
Article number138950
Journal / PublicationThin Solid Films
Volume737
Online published24 Sep 2021
Publication statusPublished - 1 Nov 2021

Abstract

Color imaging experiment demonstrates a photochromic behavior of mixed-halide perovskites upon dark and light excitation, while the color emitted by the crystals changes from red to yellow and vice versa with the intensity of excitation light source. Unlike the photochromic property commonly observed in solution-state polymer materials, solid-state perovskite materials with photochromic behavior might open wide applications in consumer products and electronic devices. In the next part, we report on a reversible photoluminescence (PL) peak in iodide-based organic-inorganic lead halide perovskite materials under a 2-photon absorption process, while tuning the excitation wavelength. Intriguingly, two shorter wavelength peaks are visible and become prominent when the excitation photon energy is being tuned in the high energy spectrum, while laser power is remained constant. The same phenomenon of reversible PL peak is also observed in various iodine-based organic-inorganic halides as well as all-inorganic perovskite single crystals and polycrystals. We attribute to the reversible PL peak phenomenon to the photoinduced structural deformation and the associated change in the optical bandgap of iodide perovskites under the femtosecond laser excitation. Our findings will introduce a degree of freedom in future research as well as adding functionalities to optoelectronic applications in these emerging perovskite materials-based devices.

Research Area(s)

  • 2-Photon absorption, Femtosecond laser, Perovskites, Photochromic, Reversible photoluminescence peak

Citation Format(s)

Reversible photochromic and photoluminescence in iodide perovskites. / Qarony, Wayesh; Hossain, Mohammad Kamal; Hossain, Mohammad Ismail; Zeng, Longhui; Ma, Sainan; Yu, Kin Man; Salleo, Alberto; Knipp, Dietmar; Yip, Cho Tung; Tsang, Yuen Hong.

In: Thin Solid Films, Vol. 737, 138950, 01.11.2021.

Research output: Journal Publications and Reviews (RGC: 21, 22, 62)21_Publication in refereed journalpeer-review